Surface Atom Core Level Shifts In The Noble Metals

G K Wertheim; P H Citrin

doi:10.1117/12.939178

27 March 1984 Surface Atom Core Level Shifts In The Noble Metals

G K Wertheim, P H Citrin

Proceedings Volume 0447, Science with Soft X-Rays; (1984) https://doi.org/10.1117/12.939178
Event: 1983 Brookhaven Conference: Science with Soft X-Rays, 1983, Upton, United States

Abstract

Photoemission with characteristic x-ray and synchrotron radiation has shown that the first atomic layers of the noble metals have electronic properties which differ from those of the bulk. The d bands are narrowed at the surface, resulting in reduced s-d hybridiza-tion and a transfer of charge from s- into d-states. These changes result in a decrease in the core electron binding energies at the surface which have been determined for all three metals.

Citation Download Citation

G K Wertheim and P H Citrin "Surface Atom Core Level Shifts In The Noble Metals", Proc. SPIE 0447, Science with Soft X-Rays, (27 March 1984); https://doi.org/10.1117/12.939178

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