Subpicosecond Fluorescence Measurements - Applications In Chemistry.

Paul F Barbara; Tai Jong Kang; Wtodzimierz Jarzeba; Michael Kahlow

doi:10.1117/12.945450

27 April 1988 Subpicosecond Fluorescence Measurements - Applications In Chemistry.

Paul F Barbara, Tai Jong Kang, Wtodzimierz Jarzeba, Michael Kahlow

Proceedings Volume 0910, Fluorescence Detection II; (1988) https://doi.org/10.1117/12.945450
Event: 1988 Los Angeles Symposium: O-E/LASE '88, 1988, Los Angeles, CA, United States

Abstract

We have recently constructed an apparatus capable of measuring time resolved emission on a subpicosecond timescale following ultraviolet excitation. Using this equipment, it is possible to study many fundamental chemical processes in fluid solution. We have studied two aspects of the chemistry of polar solutions : microscopic solvation dynamics about polar dye molecules and fast intramolecular electron transfer. Microscopic solvation relaxation appears to be the rate limiting step in the intramolecular transfer reaction of the excited state of 9,9'-bianthryl.

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Paul F Barbara, Tai Jong Kang, Wtodzimierz Jarzeba, and Michael Kahlow "Subpicosecond Fluorescence Measurements - Applications In Chemistry.", Proc. SPIE 0910, Fluorescence Detection II, (27 April 1988); https://doi.org/10.1117/12.945450

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