SPIEDL Logo

GENERAL INFORMATION

Fabrication and realistic modeling of three-dimensional metal-dielectric composites

J. Nanophoton. 5, 051513 (May 23, 2011); http://dx.doi.org/10.1117/1.3590208

Mark D. Thoreson, Jieran Fang, Alexander V. Kildishev, Vladimir M. Shalaev, and Vladimir P. Drachev

Purdue University, Birck Nanotechnology Center and School of Electrical and Computer Engineering, 1205 West State Street, West Lafayette, Indiana 47907 vdrachev@purdue.edu

Friedrich-Alexander-Universität, Erlangen Graduate School for Advanced Optical Technologies (SAOT), Erlangen-Nürnberg, Erlangen, 91052, Germany

Ludmila J. Prokopeva

Institute for Computational Technologies, Russian Academy of Sciences, Novosibirsk, 630090, Russia

Piotr Nyga

Institute of Optoelectronics, Military University of Technology, 00-908 Warsaw 49, Poland

Uday K. Chettiar

University of Pennsylvania, Department of Electrical and Systems Engineering, Philadelphia, Pennsylvania 19104

Historically, the methods used to describe the electromagnetic response of random, three-dimensional (3D), metal-dielectric composites (MDCs) have been limited to approximations such as effective-medium theories that employ easily-obtained, macroscopic parameters. Full-wave numerical simulations such as finite-difference time domain (FDTD) calculations are difficult for random MDCs due to the fact that the nanoscale geometry of a random composite is generally difficult to ascertain after fabrication. We have developed a fabrication method for creating semicontinuous metal films with arbitrary thicknesses and a modeling technique for such films using realistic geometries. We extended our two-dimensional simulation method to obtain realistic geometries of 3D MDC samples, and we obtained the detailed near- and far-field electromagnetic responses of such composites using FDTD calculations. Our simulation results agree quantitatively well with the experimentally measured far-field spectra of the real samples.

© 2011 Society of Photo-Optical Instrumentation Engineers (SPIE)

History
Received Jan 17, 2011
Accepted Apr 15, 2011
Revised Apr 14, 2011
Published online May 23, 2011
Citation
Mark D. Thoreson, Jieran Fang, Alexander V. Kildishev, Ludmila J. Prokopeva, Piotr Nyga, Uday K. Chettiar, Vladimir M. Shalaev and Vladimir P. Drachev, "Fabrication and realistic modeling of three-dimensional metal-dielectric composites", J. Nanophoton. 5, 051513 (May 23, 2011); http://dx.doi.org/10.1117/1.3590208

DOWNLOAD ARTICLE

OPEN ACCESS

FULL-TEXT OPTIONS:

RELATED CONTENT

More Like This Article


  1. C. Sella, S. Chernot, V. Reillon, and S. Berthier, “Influence of the deposition conditions on the optical absorption of Ag-SiO2 nanocermet thin films,” Thin Solid Films 517, 5848–5854 (2009).
  2. P. Reinhardt, C. Reinhardt, G. Reisse, and C. Weissmantel, “Electrical and structural properties of ion beam sputtered silver-SiO2 cermet films,” Thin Solid Films 51, 99–104 (1978). [Inspec]
  3. C. Sella, A. Bichri, J. C. Martin, J. Lafait, K. Driss-Khodja, and S. Berthier, “Adjustable optical properties of coatings based on cermet thin films near the percolation threshold,” Phys. A 157, 555–560 (1989).
  4. M. Gadenne, P. Gadenne, J. C. Martin, and C. Sella, “Composition and electrical properties of Au-A12O3 cermet thin films: A critical study,” Thin Solid Films 221, 183–190 (1992).
  5. V. M. Shalaev, M. I. Stockman, and R. Botet, “Resonant excitations and nonlinear optics of fractals,” Phys A 185, 181–186 (1992). [Inspec] [ISI]
  6. V. P. Drachev, W. D. Bragg, V. A. Podolskiy, V. P. Safonov, W. T. Kim, Z. C. Ying, R. L. Armstrong, and V. M. Shalaev, “Large local optical activity in fractal aggregates of nanoparticles,” J. Opt. Soc. Am. B 18, 1896–1903 (2001). [ISI]
  7. A. K. Sarychev, R. C. McPhedran, and V. M. Shalaev, “Electrodynamics of metal-dielectric composites and electromagnetic crystals,” Phys. Rev. B 62, 8531–8539 (2000).
  8. V. A. Podolskiy, A. K. Sarychev, E. E. Narimanov, and V. M. Shalaev, “Resonant light interaction with plasmonic nanowire systems,” J. Opt. A. Pure Appl. Opt. 7, S32–S37 (2005).
  9. A. K. Sarychev and V. M. Shalaev, “Electromagnetic field fluctuations and optical nonlinearities in metal-dielectric composites,” Phys. Rep. 335, 276–371 (2000). [ISI]
  10. D. A. Genov, A. K. Sarychev, and V. M. Shalaev, “Plasmon localization and local field distribution in metal-dielectric films,” Phys. Rev. E 67, 056611 (2003). [ISI]
  11. S. Ducourtieux, V. A. Podolskiy, S. Grésillon, S. Buil, B. Berini, P. Gadenne, A. C. Boccara, J. C. Rivoal, W. D. Bragg, K. Banerjee, V. P. Safonov, V. P. Drachev, Z. C. Ying, A. K. Sarychev, and Vladimir M. Shalaev, “Near-field optical studies of semicontinuous metal films,” Phys. Rev. B 64, 165403 (2001). [ISI]
  12. S. Ducourtieux, S. Gresillon, A. C. Boccara, J. C. Rivoal, X. Quelin, P. Gadenne, V. P. Drachev, W. D. Bragg, V. P. Safanov, V. P. Podolskiy, Z. C. Ying, R. L. Armstrong, and V. M. Shalaev, “Percolation and fractal composites: Optical studies,” J. Nonlinear Opt. Phys. Mater. 9(1), 105–116 (2000).
  13. M. Moskovits, “Surface-enhanced spectroscopy,” Rev. Mod. Phys. 57, 783–826 (1985).
  14. V. P. Drachev, M. D. Thoreson, E. N. Khaliullin, V. J. Davisson, and V. M. Shalaev, “Surface-enhanced Raman difference between human insulin and insulin lispro detected with adaptive nanostructures,” J. Phys. Chem. B 108, 18046–18052 (2004).
  15. V. P. Drachev, M. D. Thoreson, V. Nashine, E. N. Khaliullin, D. Ben-Amotz, V. J. Davisson, and V. M. Shalaev, “Adaptive silver films for surface-enhanced Raman spectroscopy of biomolecules,” J. Raman Spectrosc. 36, 648–656 (2005). [ISI]
  16. V. P. Drachev, V. C. Nashine, M. D. Thoreson, D. Ben-Amotz, V. J. Davisson, and V. M. Shalaev, “Adaptive silver films for detection of antibody-antigen binding,” Langmuir 21, 8368–8373 (2005). [MEDLINE]
  17. K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, and M. S. Feld, “Single molecule detection using surface-enhanced Raman scattering (SERS),” Phys. Rev. Lett. 78, 1667–1670 (1997).
  18. M. Osawa and M. Ikeda, “Surface-enhanced infrared absorption of p-nitrobenzoic acid deposited on silver island films: Contributions of electromagnetic and chemical mechanisms,” J. Phys. Chem. 95, 9914–9919 (1991). [ISI]
  19. A. Hartstein, J. R. Kirtley, and J. C. Tsang, “Enhancement of the infrared absorption from molecular monolayers with thin metal overlayers,” Phys. Rev. Lett. 45, 201–204 (1980).
  20. M. Osawa, “Surface-enhanced infrared absorption,” Top. Appl. Phys. 81, 163–182 (2001).
  21. D. Enders and A. Pucci, “Surface enhanced infrared absorption of octadecanethiol on wet-chemically prepared Au nanoparticle films,” Appl. Phys. Lett. 88, 184104 (2006)APPLAB000088000018184104000001.
  22. M. Westphalen, U. Kreibig, J. Rostalski, H. Lüth, and D. Meissner, “Metal cluster enhanced organic solar cells,” Sol. Energy Mater. Sol. Cells 61, 97–105 (2000).
  23. A. Yakimov and S. R. Forrest, “High photovoltage multiple-heterojunction organic solar cells incorporating interfacial metallic nanoclusters,” Appl. Phys. Lett. 80, 1667–1670 (2002)APPLAB000080000009001667000001. [ISI]
  24. D. A. Genov, A. K. Sarychev, and V. M. Shalaev, “Metal-dielectric composite filters with controlled spectral windows of transparency,” J. Nonlinear Opt. Phys. Mater. 12(4), 419–440 (2003).
  25. P. Nyga, V. P. Drachev, M. D. Thoreson, and V. M. Shalaev, “Mid-IR plasmonics and photomodification with Ag films,” Appl. Phys. B 93, 59–68 (2008).
  26. D. A. G. Bruggeman, “Calculation of various physical constants of heterogeneous substances. I. dielectric constants and conductivity of mixed bodies from isotropic substances,” Ann. Phys. 24, 636–679 (1935) (in German).
  27. P. Sheng, “Theory of the dielectric function of granular composite media,” Phys. Rev. Lett. 45, 60–63 (1980). [ISI]
  28. R. B. Nielsen, M. D. Thoreson, W. Chen, A. Kristensen, J. M. Hvam, A. Boltasseva, and V. M. Shalaev, “Toward superlensing with metal-dielectric composites and multilayers,” Appl. Phys. B 100, 93–100 (2010).
  29. A. Taflove and S. C. Hagness, Computational Electromagnetics: The Finite Difference Time Domain Method (Artech House, Norwood, Massachusetts, 2000).
  30. U. K. Chettiar, P. Nyga, M. D. Thoreson, A. V. Kildishev, V. P. Drachev, and V. M. Shalaev, “FDTD modeling of realistic semicontinuous metal films,” Appl. Phys. B 100, 159–168 (2010).
  31. A. V. Kildishev, U. Chettiar, and V. M. Shalaev, “Simulation of optical negative index materials using parallel FDTD method,” Proceedings of the 22nd Annual Review of Progress in Applied Computational Electromagnetics, ACES, Miami, FL (2006).
  32. T. Grosges, A. Vial, and D. Barchiesi, “Models of near-field spectroscopic studies: comparison between finite-element and finite-difference methods,” Opt. Express 13(21), 8483–8497 (2005).
  33. L. J. Prokopeva, J. Borneman, and A. V. Kildishev, “Optical dispersion models for time-domain modeling of metal-dielectric nanostructures,” IEEE Trans. Magn. 47(5), 1150–1153 (2011).
  34. P. B. Johnson and R. W. Christy, “Optical constants of the noble metals,” Phys. Rev. B 6, 4370–4379 (1972).
  35. V. P. Drachev, U. K. Chettiar, A. V. Kildishev, H. K. Yuan, W. Cai, and V. M. Shalaev, “The Ag dielectric function in plasmonic metamaterials,” Opt. Express 16, 1186–1195 (2008). [MEDLINE]
  36. K. P. Chen, V. P. Drachev, J. D. Borneman, A. V. Kildishev, and V. M. Shalaev, “Drude relaxation rate in grained gold nanoantennas,” Nano Lett. 10, 916–922 (2010). [MEDLINE]
  37. T. J. Miller, “Monitoring TOC in UPW at the Birck Nanotechnology Center,” Ultrapure Water-Micro, Phoenix, AZ (2010).
  38. M. Ohring, Materials Science of Thin Films: Deposition and Structure, Academic Press, San Diego, (2001)
    J. A. Venables, G. D. T. Spiller, and M. Hanbucken, “Nucleation and growth of thin films,” Rep. Prog. Phys. 47, 399–459 (1984).
  39. S. L. Storm, A. Springsteen, and T. M. Ricker, “The use of center mount sample holders in reflectance spectroscopy,” Labsphere Application Note No. 02 (1998).
  40. Persistence of VisionTM Raytracer (Version 3.62), Persistence of Vision Pty. Ltd., Williamstown, Victoria, Australia, www.povray.org.
  41. J. Schmitt, G. Decher, W. J. Dressick, S. L. Brandow, R. E. Gee, R. Shashidhar, and J. M. Calvert, “Metal nanoparticle/polymer superlattice films: fabrication and control of layer structure,” Adv. Mater 9(1), 61–65 (1997). [Inspec] [ISI]
  42. J. Werner, A. Heilmann, V. Hopfe, F. Homilius, B. Steiger, and O. Stenzel, “Changes of the optical properties of plasma polymer silver composite films caused by laser-annealing,” Thin Solid Films 237, 193–199 (1994). [Inspec] [ISI]
  43. H. Takele, S. Jebril, T. Strunskus, V. Zaporojchenko, R. Adelung, and F. Faupel, “Tuning of electrical and structural properties of metal-polymer nanocomposite films prepared by co-evaporation technique,” Appl. Phys. A 92, 345–350 (2008).
  44. H. Takele, H. Greve, C. Pochstein, V. Zaporojtchenko, and F. Faupel, “Plasmonic properties of Ag nanoclusters in various polymer matrices,” Nanotechnology 17(14), 3499–3505 (2006). [MEDLINE]
  45. J. Schuster and R. Luebbers, “An accurate FDTD algorithm for dispersive media using a piecewise constant recursive convolution technique,” IEEE Antennas Propagat. Soc. Int. Symp., Atlanta, GA, pp. 2018–2021 (1998).


Close

close