Resonance Raman Studies Of Copper(II) Octaethylisobacteriochlorin

David F. Bocian; Alexander D. Procyk; Jeffrey M. Peloquin

doi:10.1117/12.951657

8 May 1989 Resonance Raman Studies Of Copper(II) Octaethylisobacteriochlorin

David F. Bocian, Alexander D. Procyk, Jeffrey M. Peloquin

Proceedings Volume 1057, Biomolecular Spectroscopy; (1989) https://doi.org/10.1117/12.951657
Event: OE/LASE '89, 1989, Los Angeles, CA, United States

Abstract

Resonance Raman spectra are reported for the copper(II) complex of trans-octaethylisobacteriochlorin with excitation in the B and Qy absorption bands. Assignments are proposed for a number of the high-frequency (above 1400 cm-1) skeletal modes of the macrocycle. Normal coordinate calculations are also performed on the complex. These calculations indicate that the normal coordinates of isobacteriochlorins bear little resemblance to those of porphyrins or chlorins.

Citation Download Citation

David F. Bocian, Alexander D. Procyk, and Jeffrey M. Peloquin "Resonance Raman Studies Of Copper(II) Octaethylisobacteriochlorin", Proc. SPIE 1057, Biomolecular Spectroscopy, (8 May 1989); https://doi.org/10.1117/12.951657

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