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Eu doped CaAlSiN3 phosphor was successfully prepared by high-temperature solid phase method using Ca2Si5N8:Eu as major raw materials. The phase transition and luminescence properties were studied in detail. It is found that the phase changes from Ca2Si5N8 to CaSiN2 when the temperature reaches 800 ℃. Then CaAlSiN3:Eu phosphor was synthesized by the solid phase reaction: (Ca,Eu)SiN2+AlN→(Ca,Eu)AlSiN3 when the reaches 1500 ℃. The morphology and luminescence properties of CaAlSiN3: Eu with different Eu concentration was also studied.
Lei Chen,Gang Jing,Yan Liu, andJintian Lin
"Study on preparation mechanism and luminescence property of CaAlSiN3: Eu phosphor", Proc. SPIE 11885, International Conference on Laser, Optics and Optoelectronic Technology (LOPET 2021), 118850W (24 June 2021); https://doi.org/10.1117/12.2602405
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Lei Chen, Gang Jing, Yan Liu, Jintian Lin, "Study on preparation mechanism and luminescence property of CaAlSiN3: Eu phosphor," Proc. SPIE 11885, International Conference on Laser, Optics and Optoelectronic Technology (LOPET 2021), 118850W (24 June 2021); https://doi.org/10.1117/12.2602405