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Photoluminescence effect was found in Zr-based fluoride glass preforms and fibres doped with Nd, Eu and Er under excitation with Kr-ion laser. Generation of visible to middle infrared including 2.7 pm were observed. Er-doped fluoro-zirconate fibre is capable to lase many desired wavelengths.
Gorachand Ghosh
"Photoluminescence in fluoride glass optical fibres", Proc. SPIE 1230, International Conference on Optoelectronic Science and Engineering '90, 12304W (1 July 1990); https://doi.org/10.1117/12.2294813
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Gorachand Ghosh, "Photoluminescence in fluoride glass optical fibres," Proc. SPIE 1230, International Conference on Optoelectronic Science and Engineering '90, 12304W (1 July 1990); https://doi.org/10.1117/12.2294813