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We report two types of the tin-based solar cells, namely, lead-free tin perovskite solar cells (Sn-PVK-PV), tin lead alloyed perovskite solar cells (SnPb-PVK-PV). Tin oxide is well-known as the electron transport layer of solar cells such as Pb-PVK PV, dye-sensitized solar cells and organic solar cells. We found that SnOx works as the HTL of the Sn-PVK PV. The basic structure is as follows: FTO glass/SnOx/Sn-PVK/C60/BCP/Ag. Efficiency over 14% and the carrier dynamics are reported. All-perovskite tandem solar cells consisting of Pb-PVK-PV (top cell) and PbSn-PVK-PV (bottom cells) are reported. PbSn-PVK PV efficiency was improved by using hybrid SAM layers working as the HTL. The efficiency over 26% is reported.
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(2023) Published by SPIE. Downloading of the abstract is permitted for personal use only.
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Shuzi Hayase, Liang Wang, Takeshi Kitamura, Huan Bi, Gaurav Kapil, Hiroshi Segawa, Saulius Grigalevicius, "Tin based perovskite solar cells and all-perovskite tandem solar cells," Proc. SPIE 12660, Organic, Hybrid, and Perovskite Photovoltaics XXIV, 1266005 (1 October 2023); https://doi.org/10.1117/12.2678067