Fourier transform infrared and FT-Raman studies on tetranuclear oxo-centered carboxylate complexes of zinc

O. Berkesi; I. Dreveni; J. A. Andor; U. A. Jayasooriya; R. D. Cannon; J. Mink

doi:10.1117/12.166781

31 January 1994 Fourier transform infrared and FT-Raman studies on tetranuclear oxo-centered carboxylate complexes of zinc (II)

O. Berkesi, I. Dreveni, J. A. Andor, U. A. Jayasooriya, R. D. Cannon, J. Mink

Author Affiliations +

Proceedings Volume 2089, 9th International Conference on Fourier Transform Spectroscopy; (1994) https://doi.org/10.1117/12.166781
Event: Fourier Transform Spectroscopy: Ninth International Conference, 1993, Calgary, Canada

Abstract

A selection of stable Zn₄O(RCOO)₆ complexes have been studied by FT-IR and FT- Raman spectroscopy. Polarized FT-Raman studies of two samples, which were in liquid state at ambient temperature, have also been completed. An attempt was made to construct the kinetic energy matrix for a simplified model involving 29 atoms with T_d symmetry. A set of symmetry coordinates was chosen to describe the vibrational behavior of the molecule and serve as a base for future force-field calculations. The characteristic frequencies of A₁ and T₂ species were assigned. Some of the E modes were also obtained.

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O. Berkesi, I. Dreveni, J. A. Andor, U. A. Jayasooriya, R. D. Cannon, and J. Mink "Fourier transform infrared and FT-Raman studies on tetranuclear oxo-centered carboxylate complexes of zinc (II)", Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); https://doi.org/10.1117/12.166781

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