Paper
12 February 1997 Chemically enhanced FIB repair of opaque defects on molybdenum silicide photomasks
J. David Casey Jr., Andrew F. Doyle, Diane K. Stewart, David C. Ferranti, Mark L. Raphaelian, John C. Morgan
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Abstract
The characteristics of an ideally repaired opaque defect on a molybdenum silicide (MoSiaObNc) photomask are: (1) the total removal of the MoSiaObNc defect, leaving no residual MoSiaObNc; (2) a smooth, level quartz surface (no over-etch) after the MoSiaObNc is removed; (3) minimal riverbedding of the quartz at the perimeter of the MoSiaObNc defect; and (4) maximum light transmission (%T) at the i-line (365 nm) and DUV (248 nm) lithographic wavelengths. Achieving these ideal repair characteristics is becoming increasingly difficult as the patterned features become smaller, as the lithographic wavelength becomes shorter and as phase shifting mechanisms are implemented. A chemical process has been developed to enhance the FIB (focused ion beam) etching of MoSiaObNc defects. Using this chemical process, a FIB protocol has been developed which enhances the removal of a MoSiaObNc defect while inhibiting the removal of quartz. AFM (atomic force microscopy) indicates that (1) MoSiaObNc is totally removed, (2) the quartz remains smooth and level (no over-etch), and (3) the riverbends are, at this time, 10 - 45 nm; our target is 1 - 15 nm. The MoSiaObNc etch process reduces optical staining due to implanted gallium
© (1997) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
J. David Casey Jr., Andrew F. Doyle, Diane K. Stewart, David C. Ferranti, Mark L. Raphaelian, and John C. Morgan "Chemically enhanced FIB repair of opaque defects on molybdenum silicide photomasks", Proc. SPIE 3236, 17th Annual BACUS Symposium on Photomask Technology and Management, (12 February 1997); https://doi.org/10.1117/12.301221
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Cited by 8 patents.
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KEYWORDS
Quartz

Opacity

Photomasks

Gallium

Etching

Molybdenum

Carbon

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