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The solubility of rare earths at a level of 0.5 mol% in traditional heavy metal oxide glasses based on bismuth, lead and gallium is limited to the largest cations Pr, Nd and Sm. Within the families of these oxide glasses, a higher level of doping was achieved in this work with a heavy metal oxide glass containing germanium as a fourth component. Spectroscopic studies on the Nd3+ doped glasses revealed that the fluorescence peak for the 1.3 micrometer transition occurred at a relatively long wavelength of about 1360 nm. Decay time constants for the 4F3/2 level were considerably shorter than in other host materials.
Douglas R. MacFarlane,Peter J. Newman,Ruth Plathe, andDavid J. Booth
"Heavy metal oxide glasses as active materials", Proc. SPIE 3849, Infrared Optical Fibers and Their Applications, (10 December 1999); https://doi.org/10.1117/12.372790
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Douglas R. MacFarlane, Peter J. Newman, Ruth Plathe, David J. Booth, "Heavy metal oxide glasses as active materials," Proc. SPIE 3849, Infrared Optical Fibers and Their Applications, (10 December 1999); https://doi.org/10.1117/12.372790