Variable Temperature FTIR Spectroscopy Of Inorganic Cyanide Complexes

D. Melick; R. H . Herber

doi:10.1117/12.970879

20 December 1985 Variable Temperature FTIR Spectroscopy Of Inorganic Cyanide Complexes

D. Melick, R. H . Herber

Proceedings Volume 0553, Fourier and Computerized Infrared Spectroscopy; (1985) https://doi.org/10.1117/12.970879
Event: 1985 International Conference on Fourier and Computerized Infrared Spectroscopy, 1985, Ottawa, Canada

Abstract

Variable temperature Fourier transform infrared spectroscopy can be used as a sensitive technique for the study of intermolecular bonding forces in solids. Because of the different types of bonding interactions possible for the cyanide moiety and the large oscillator strength of the CN stretching frequency, the infrared active vibrations of this group can serve as a diagnostic reporter entity for the study of a wide variety of inorganic cyanide complexes. The temperature dependence of vcN over the range 78 < T < 300 K are reported in the present study.

Citation Download Citation

D. Melick and R. H . Herber "Variable Temperature FTIR Spectroscopy Of Inorganic Cyanide Complexes", Proc. SPIE 0553, Fourier and Computerized Infrared Spectroscopy, (20 December 1985); https://doi.org/10.1117/12.970879

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