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This PDF file contains the front matter associated with SPIE
Proceedings Volume 6459, including the Title Page, Copyright
information, Table of Contents, Introduction (if any), and the
Conference Committee listing.
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The main focus of this article lies on the development of a novel joining technology for LTCC ceramic and
polymer sub-assemblies utilising laser radiation. Technical processes and the latest results are presented as
well as potential future applications. The developed joining process can be divided into two steps utilizing
the same laser system: a surface modification of the joining partners and a thermal process that is melting a
small portion of the polymer matrix that is being pressed into the roughness of the ceramic surface.
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Most welding processes for plastics do not meet the demands of micro technology and thus cannot be applied in this
innovative industrial sector. One of the few techniques which are applicable in this sector is the laser transmission
welding, which has distinctive advantages like low mechanical and thermal load of the joining parts. This makes the
laser particularly suitable for the welding of micro plastics parts. Thereby, contour welding is a process variant of laser
transmission welding enabling the welding of complex and even three-dimensional weld contours. But so far it has not
yet been applied for welding plastics parts of micro scale in the industrial practice. Recent research at the Institute of
Plastics Processing (IKV) at the RWTH Aachen University shows the feasibility of this process to weld small and
complex micro parts. Good mechanical properties can be achieved. However, it is necessary to apply measures to reduce
the formation of flash. Moreover, it can be shown that there is a strong influence of some material parameters on the
laser welding process so that some plastics are more suitable than others for the contour welding in micro technology.
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Longterm stable and high precise interconnections between small optical components and the optomechanical platform
are mandatory for the assembly of complex and miniaturized optoelectronical systems. The approach discussed in this
paper is to integrate optics and electronics on a common platform that is a ceramic Printed Circuit Board with embedded
mounting structures for easy passive alignment of the optical components. Active alignment with higher accuracy can
also be used, in both cases laserbeam soldering is the preferred and precise joining technology. Thin solder layers as well
as solder bumps are used to create joints with an accuracy <±0.5 &mgr;m, suitable for singlemode coupling applications.
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Despite the electronic manufacturing is well-established mass production process for a long time, the problem of
reworking, i.a. reject and replace of defect components, still exists. The rework operations (soldering, replacement and
desoldering) are performed in most cases manually. However, this practice is characterized by an inconsistent quality of
the reworked solder joints and a high degree of physiological stress for the employees.
In this paper, we propose a novel full-automated laser based soldering and rework process. Our developed soldering
system is a pick-and-place unit with an integrated galvanometer scanner, a fiber coupled diode laser for quasi-simultaneous
soldering and a pyrometer-based process control. The developed system provides soldering and reworking
processes taking into account a kind of defect, a type of electronic component and quality requirements from the IPC-
610 norm.
The paper spends a great deal of efforts to analyze quality of laser reworked solder joints. The quality depends mainly
on the type and thickness of intermetallic phases between solder, pads and leads; the wetting angles between pad, solder
and lead; and finally, the joint microstructure with its mechanical properties. The influence of the rework soldering on
these three factors is discussed and compared to conventional laser soldering results. In order to optimize the quality of
reworked joints, the different strategies of energy input are applied.
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In this paper we will discuss various aspects of surface engineering. This is a broad term, and we choose to focus on two
aspects thereof, namely surface texturing on the micron scale using laser micromachining, and chemical modification of
the surface using molecular vapour deposition (MVD). First, we will discuss the basics of laser texturing, followed by a
brief review of contact angle theory. We will then demonstrate how to obtain superhydrophobic surfaces on any kind of
material using a combined laser and MVD process. Finally, we will present a few recent industrial cases.
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Laser-assisted patterning of polymers is investigated for the direct fabrication of polymeric lab-on-a-chip devices in
microsystem technology for capillary electrophoresis chips in bio-analytical applications. In many cases the laser
process induces a chemical, physical and topographical change in the laser treated surface. This material modification
significantly influences the lab-on-a-chip-functionalities. We will present our current research results in laser-assisted
modification of polystyrene (PS) and polymethylmethacrylate (PMMA) with respect to applications in micro-optics,
micro-fluidics and cell culture applications. For this purpose the refractive index change, the wettability and the
adsorption of proteins and the adhesion of animal cells were investigated as function of laser- and processing
parameters. The possible change of surface chemistry was characterized by X-ray photoelectron spectroscopy.
The local UV-laser-assisted formation of chemical structures suitable for improved cell adhesion was realized on two-
and three-dimensional PS and polycarbonate (PC) surfaces. Above and below the laser ablation threshold two different
mechanisms were detected. In one case the produced debris was responsible for improved cell adhesion, while in the
other case a photolytical activation of the polymer surface including a subsequent oxidization in oxygen or ambient air
leads to a highly localized alteration of protein adsorption from cell culture media and increased cell adhesion.
The highly localized control of wettability on polymeric surfaces was investigated for PS and PMMA. In the case of PS
the dynamic advancing contact angle could be adjusted between 2° and 150°. This was possible for a suitable exposure
dose and an appropriate choice of processing gas (helium or oxygen). A similar but not so significant effect was
observed for PMMA below the laser ablation threshold. For PMMA the dynamic advancing contact angle could be
adjusted between nearly 50° and 80°. The adjustment of wettability for microfluidic application will be discussed.
For the integration of integrated optical waveguides in micro-fluidic devices new approaches for a rapid manufacturing
of optical singlemode waveguides made of PMMA were investigated. For this purpose a high repetition excimer laser
radiation source was used in combination with a flexible mask technology. The waveguides were characterized for the
visible optical range and for 1559 nm. The obtained structures reveal absorption losses of 0.7 dB/cm in the visible
range.
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As a sequential production method, laser technology is considered not to be a competitor to established plastic processing methods, but instead is used whenever small numbers or just mere prototypes are required. Laser ablation by UV-excimer lasers is a flexible and accurate tool for the manufacturing of polymeric micro-fluidic parts. Even soft and flexible materials like PDMS that are difficult to machine with conventional techniques can be structured by laser ablation with great precision and quality. Sealing of polymer parts by laser beam welding leads to a complete production cycle for small series and prototypes. A further application of UV-excimer lasers is the production of so called "lost moulds" for the production of filigree microstructures. Micro-pillars are fabricated by drilling holes in wax masters using excimer laser radiation and subsequent casting with PDMS. Frictionless demolding is achieved by melting the wax away. The fabricated PDMS micro-pillar arrays can be used for shear stress and flow rate sensors due to bending of the flexible posts. In combination with laser ablation techniques micro-fluidic devices with new properties can be fabricated.
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Optical biochips may incorporate both optical and microfluidic components as well as integrated light emitting
semiconductor devices. They make use of a wide range of materials including polymers, glasses and thin metal films
which are particularly suitable if low cost devices are envisaged. Precision laser micromachining is an ideal flexible
manufacturing technique for such materials with the ability to fabricate structures to sub-micron resolutions and a
proven track record in manufacturing scale up.
Described here is the manufacture of a range of optical biochip devices and components using laser micromachining
techniques. The devices employ both microfluidics and electrokinetic processes for biological cell manipulation and
characterization. Excimer laser micromachining has been used to create complex microelectrode arrays and microfluidic
channels. Excimer lasers have also been employed to create on-chip optical components such as microlenses and
waveguides to allow integrated vertical and edge emitting LEDs and lasers to deliver light to analysis sites within the
biochips.
Ultra short pulse lasers have been used to structure wafer level semiconductor light emitting devices. Both surface
patterning and bulk machining of these active wafers while maintaining functionality has been demonstrated. Described
here is the use of combinations of ultra short pulse and excimer lasers for the fabrication of structures to provide ring
illumination of in-wafer reaction chambers.
The laser micromachining processes employed in this work require minimal post-processing and so make them ideally
suited to all stages of optical biochip production from development through to small and large volume production.
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Using excimer laser with 248 nm wavelength, we have been developed the 45-degree micro-mirrors in the polymer
optical waveguide constructed by newly developed epoxy resin. The three-dimensional laser processing technology for
controlling the mask aperture size on the laser beam is effective for fabricating the 45-degree mirror. The size of the
mirror was about 80 micrometer width. Although the periodical micro patterns have appeared on the surface of the
mirrors, we have successfully removed the patterns by the technique of smoothing. Smoothing process has been carried
out by the additional laser irradiation with weak and/or strong energy. The obtained surface roughness of the mirrors was
less than 120 nm (Ry). The evaluation of the optical loss using laser with 670 nm wavelength resulted in the less than 0.5
dB, indicating sufficient mirror performance.
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This paper describes experimental and numerical results of the
plasma-assisted microfabrication of subwavelength structures by
means of point-by point femtosecond laser inscription. It is shown
that the spatio-temporal evolution of light and plasma patterns
critically depend on input power. Subwavelength inscription
corresponds to the supercritical propagation regimes when pulse
power is several times self-focusing threshold. Experimental and
numerical profiles show quantitative agreement.
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Optical elements with subwavelength structures (SWSs) may function as anti-reflection layers, wave plates, or
polarizers. In this study, the authors focus on a pair of two-beam interference lithography systems for fabricating SWS
optical elements. These systems have different optical configurations for forming the interference fields required for
exposure. The first lithography system described herein creates an interference field by splitting a laser beam with a half-mirror
and then superimposing the two resulting beams on a substrate after they propagate through free space. A resist
pattern with a period of 140 nm is formed across a 4-inch substrate using a 266-nm CW laser. The other lithography
system employs a high-density holographic grating. The two diffracted light waves (0th order and 1st order) produced by
the holographic grating generate an interference field in close proximity to the holographic grating, thus enabling a more
compact exposure system and a stable lithography process. The desired nano-pattern is obtained by exposing the resist
with the 266-nm CW laser using a 140-nm-pitched holographic grating. This research demonstrates the potential of two-beam
interference lithography as a viable process for manufacturing SWS optical elements used with the visible
spectrum.
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A solid-state UV laser was used to make arrays of reproducible percussion-drilled micron-sized holes in polyimide. An optical switch was employed as a pulse picker to select specific patterns of pulses from the high repetition rate laser beam. The ability to control and vary the number of pulses per burst and the time between bursts enhanced the drilling rate while minimizing thermal damage around the holes. The optimum pulse patterns were determined experimentally. A photodiode acted as a breakthrough sensor to end the drilling and optimize the exit hole size and quality. Results were compared with computer simulations of the drilling process based on modeling of the laser/material interaction.
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It has been shown that micromachining of polyimide using a mode-locked high repetition rate, 80 MHz, 355nm laser is more efficient than the q-switched laser at same wavelength and same power level in terms of material removal rate. In this study we have explored and characterized the benefits of using high repetition rate, high average power, 355 nm mode-locked and q-switched lasers for micromachining of various microelectronics packaging materials that have different thermal properties. The removal rate and quality of machining have been analyzed against the difference in thermal properties of the material. The implications of the results observed are also discussed from practical manufacturing perspective.
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High power excimer lasers are well established as work horses for various kinds of micro material processing. The
applications are ranging from drilling holes, trench formation, thin film ablation to the crystallization of amorphous-Si
into polycrystalline-Si. All applications use the high photon energy and large pulse power of the excimer technology.
The increasing demand for micro scale products has let to the demand for UV lasers which support high throughput
production.
We report the performance parameters of a newly developed XeCl excimer laser with doubled repetition rate compared
to available lasers. The developed laser system delivers up to 900 mJ stabilized pulse energy at 600 Hz repetition rate.
The low jitter UV light source operates with excellent energy stability. The outstanding energy stability was reached by
using a proprietary solid-state pulser discharge design.
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Over the recent years the novel fiber laser technology and its potentials have been exciting laser manufacturers as well as
researchers and industrial users. Fiber lasers with their excellent beam quality promised noticeable advantages and
improvements in high precision and micro material processing. Besides the excellent beam quality there are more
advantages of the fiber laser technology such as compact installation size, high laser efficiency, moderate system price
and easy to be integrated. The paper presents the results of extensive comparative tests of short pulse fiber laser systems
and a common q-switch rod solid state laser with nearly identical system parameters. The intention was to determine the
specific advantages in practical application work. Where are the advantage and how large are the improvements?
Therefore typical applications of laser micro machining have been chosen - drilling, cutting and lateral material removal
as well as marking. By choosing different materials like aluminum, silicon and ruby a broad field has been examined.
Distinct improvements have been proven in several applications especially regarding precision and surface quality of the
created structures. Under almost identical conditions the fiber laser achieved more narrow cutting kerfs and smaller hole
diameters compared to the rod laser system.
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Laser trimming of microelectronics devices has enabled the fabrication of high precision and high performance components and networks. Market demands for decreasing package size and higher performance components have pushed the current laser trimming technology to its limits. To meet the challenges, laser trimming system manufacturers have been working on the new generation based on significant advances in laser technology, software tools, and related system technologies. These new systems can achieve higher accuracy needed for processing devices with ever shrinking dimensions and tighter tolerances while offering maintenance-free operation and flexibility in today's demanding production environments. We will present in this paper the latest advancement of laser based trimming systems. Future directions will also be discussed.
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Photovoltaics has in the last five years enjoyed unprecedented growth and acceptance as part of the worldwide energy mix. Innovations in both wafered silicon and various thin-film PV technologies anticipated in the next 5-10 years promise to lower the cost of PV power to parity with that supplied by the grid. When that occurs, the growth of the industry will be pulled even more strongly by market demand. A challenge in meeting this growth will be the availability of automated production equipment that can streamline the solar cell manufacturing process. Laser processing offers the potential to provide several facets of that high-volume manufacturing solution. This paper provides an overview of PV technologies, discusses current and emerging laser processes for PV manufacturing, and highlights some of the challenges for laser technology and systems that must be met to fulfill this promise.
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Optical damage produced by femtosecond pulsed lasers on dielectric surfaces is extremely precise, allowing the damage mechanisms to be inferred from reproducible damage characteristics. Here nanoscale femtosecond laser ablation is applied to probe the ultrafast dynamics of laser energy deposition including the generation and transport of surface electron-hole or electron-ion plasmas. For shallow surface nano-craters fabricated on quartz and glass surfaces by single 0.53 &mgr;m or 1.05 &mgr;m laser shots, their corresponding well-defined laser intensity thresholds demonstrate pronounced effects of laser wavelength, crystalline state of the dielectric and laser waist radius, indicating equal importance of laser energy deposition and transport phenomena during ablation. Simultaneously, unusually deep surface nanoholes emerge drilled by self-focusing laser beam or forward-scattered highly penetrating short-wavelength radiation from the warm, dense surface plasma.
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The advent of commercial grade picosecond and femtosecond lasers has opened the way for laser micromachining
of metals. There has however been no or little work reported on the ceramics. Use of diamond saws is still the
preferred way of cutting the ceramics such as an Al2O3-TiC composite (referred to as N58 hereafter) that is widely
used in the manufacture of read/write heads for magnetic recording hard disk drives. These read/write heads are
commonly referred to as "sliders".
We report here attempts to cut rows of sliders using various lasers. The cut length was 0.85 mm and the thickness
was 0.23 mm. We found that all the nanosecond pulse range lasers, left slag at the laser input edge of the cut and on
the cut wall. In many cases the slag deposit doesn't allow one to cut through the entire thickness as the slag
interferes with successive laser pulses.
Our best results were obtained with picosecond and femtosecond lasers. We were able to cut through entire
thickness of the strip with these lasers. The slag was much less than that from the nanosecond lasers, but not low
enough for our application. There were slag deposits or loose-appearing material on the cut walls also. The
roughness was at best in the micron range.
In all the cases studied the cut quality as measured by cut surface roughness and slag formation as well as the
cutting speed was worst than that obtained from the diamond saws currently used in the industry.
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The field of laser micromachining is highly diverse. There are many different types of lasers available in the market.
Due to their differences in irradiating wavelength, output power and pulse characteristic they can be selected for
different applications depending on material and feature size [1]. The main issues by using these lasers are heat
damages, contamination and low ablation rates. This report examines on the application of the Laser MicroJet(R) (LMJ), a
unique combination of a laser beam with a hair-thin water jet as a universal tool for micro-machining of MEMS
substrates, as well as ferrous and non-ferrous materials. The materials include gallium arsenide (GaAs) & silicon wafers,
steel, tantalum and alumina ceramic. A Nd:YAG laser operating at 1064 nm (infra red) and frequency doubled 532 nm
(green) were employed for the micro-machining of these materials.
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Laser-induced formation of functional materials from glasses has a great potential for creation of monolithic and high-performance
glass-based devices, such as optical circuit and micro-TAS. We have recently developed a laser-induced
formation technique of photocatalytic titanium oxide on a UV-absorbing TiO2-SiO2- based glass surface by excimer laser
irradiation under a specific condition, which we term laser-induced superficial phase separation. The laser-induced
structure has the shape of micro-cones, growing into micro-sized network after accumulating laser pulses, which we call
TiO2 micronetwork. The TiO2 micronetwork exhibited the rutile crystalline phase and photocatalytic ability. Moreover,
the crystalline phase can be controlled from the rutile to the anatase by post-treatments. Utilizing this technique, we were
able to make a site-selective growth of TiO2 micronetworks: a microwell array and a microchannel modified with the
TiO2 network only on the bottom. This flexible formation of photocatalytic TiO2 onto a glass surface without any heat-treatments
and/or adhesives opens a new way to develop a monolithic glass device like micro-fluidics with light-catalyzed
reactions.
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Laser supported processes can be used to modify the electrical and thermal properties of ceramic substrates locally.
These processes are characterised by a strong thermal interaction between the laser beam and the ceramic surface which
leads to localised melting. During the dynamic melting process metal particles are introduced into the melt pool in order
to modify the physical properties. Different alumina samples were treated with metal powders of tungsten, copper, and
oxides of these metals. The interface between the metal and the ceramic can be designed by using selected combinations
of metal- and metal-oxide-powders and also by a thermal post-processing. The application of nano-particles during the
laser-dispersing process resulted in completely different characteristics of the micro-structure and the electrical
properties compared to the conventional metal powders with an average grain size of 5 - 15 microns. The micron sized
metal particles are embedded within the ceramic matrix as particle agglomerates or as distinct metal phase the nano-particle
phase covers the grain boundaries of the ceramics leading to network of nano-scaled electrically conducting
"wires". The resulting resistance of the laser tracks can be adjusted from semi-conducting to metallic behavior with a
resistivity down to 2x10-6W/m. The modified ceramic can be used for heating elements working at operation
temperatures of up to 1000oC, high current resistances which can be loaded with currents of up to 100 A.
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Recent prominent progresses in synthesizing and manipulating single-walled carbon nanotubes (SWNTs) stimulated
extensive interests in developing SWNT-based devices for nanoelectronics and nanoelectromechanical systems (NEMS).
Thermal chemical vapor deposition (CVD) is one of the most widely accepted technique for growing SWNTs by heating
the whole chamber and substrate to required reaction temperatures. In this study, we demonstrated a process for position-controllable
synthesis of SWNT-FET by bridging the SWNT across pre-defined electrodes using the laser chemical
vapor deposition (LCVD) technique. The SWNT-FET was back-gate modulated, showing p-type semiconducting
characteristics. The process is very fast and can be conducted using both far-infrared CO2 laser (10.6 &mgr;m) and near-infrared
Nd:YAG laser (1064 nm). We have also demonstrated localized synthesis of SWNTs by a focused laser beam.
Due to the unique advantages of LCVD process, such as fast and local heating, as well as its potential to select chiralities
during the growing process, it may provide new features and versatilities in the device fabrication.
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Currently, enhancement of Raman scattering for nanoscale characterization is mostly based on tip- or surface-enhanced
methods. However, both approaches have some dilemmas which impede their wide applications. In this study, we
investigated a novel approach to enhance Raman scattering using closely-packed micro and submicro silica spherical
particles. The enhancement phenomena haven been demonstrated by the silicon phonon mode of crystalline silicon (c-Si)
substrates as well as the vibration modes of single-walled carbon nanotubes (SWCNTs) covered with microparticles. The
studies show that the enhancement effects strongly depend on the particle size. Specifically, when the particle size is
close to the beam waist of the incident laser, the strongest enhancement occurs. Numerical simulations are performed to
calculate electric field distribution inside and outside the dielectric particles using the OptiwaveTM software which is
based on the finite difference time domain (FDTD) algorithm under the perfectly matched layer (PML) boundary
conditions. The simulated results reveal the existence of photonic nanojects in the vicinity outside the particles along
with the light traveling direction. The nanojets outside of the particles with a length of 100 nm and a waist of 120 nm are
believed to be the base for Raman scattering enhancement. This technique has potential applications in many areas such
as surface science, biology, and microelectronics.
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Lasers are capable of delivering energy to a metal to induce stresses from the thermal gradient through the
material. Under the right conditions these stresses can cause the metal to bend. Experiments were conducted to produce
bending in the metal, Neyoro® G, and samples with a titanium coating on one side. In the experiments, both upward and
downward bending was observed. The titanium coated samples showed potential to be more controllable than the
uncoated samples.
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The low temperature fabrication of active (field effect transistor) electrical components on flexible polymer substrates
is presented in this paper. A drop-on-demand (DOD) ink-jetting system was used to print gold nano-particles
suspended in organic solvent, PVP (poly-4-vinylphenol) in PGMEA (propylene glycol monomethyl ether acetate)
solvent, semiconductor polymer in organic solvent to fabricate passive and active electrical components on flexible
polymer substrates. Short pulsed laser ablation enabled finer electrical components to overcome the resolution
limitation of inkjet deposition. Continuous Argon ion laser was irradiated locally to evaporate the carrier solvent as
well as to sinter gold nano-particles. In addition, a new method for the selective ablation of multilayered gold
nanoparticle film was demonstrated.
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Laser radiation is used both for the deposition of the laser active thin films and for the micro structuring to define wave guiding structures for the fabrication of waveguide lasers. Thin films of Er:ZBLAN (a glass consisting of ZrF4, BaF2, LaF3, AlF3, NaF, ErF3) for green upconversion lasers (545 nm), Nd:YAG (Y3Al5O12) and Nd:GGG (Gd3Ga5O12) for infrared lasers (1064 nm) are produced. Manufacturing of the laser active waveguides by micro-structuring is done using fs laser ablation of the deposited films. The structural and optical properties of the films and the damping losses of the structured waveguides are determined in view of the design and the fabrication of compact and efficient diode pumped waveguide lasers. The resulting waveguides are polished, provided with resonator mirrors, pumped using diode lasers and characterized.
Laser operation of a ridge waveguide structure grown by pulsed laser deposition and structured by fs laser ablation is demonstrated. A 1 &mgr;m thick, 100 &mgr;m wide and 3 mm long structured waveguide consisting of amorphous neodymium doped Gd3Ga5O12 has shown laser activity at 1.068 &mgr;m when pumped by a diode laser at 808 nm.
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We report the successful fabrication of layers of functionalized nanoparticles using a novel infrared, laser-based
deposition technique. A frozen suspension of nanoparticles was ablated with a laser tuned to a vibrational mode of the
solvent, resulting in the disruption of the matrix and ejection of the nanoparticles. The solvent was pumped away and
the nanoparticles collected by a receiving substrate in a conformal process. Photoluminescence measurements of
nanoparticles containing two common dyes showed no significant change to the emission properties of either dye,
suggesting that no damage occurred during the laser ablation process. The process is generally applicable to particles of
various sizes, shapes, and chemistries provided that an appropriate solvent is chosen. Deposition through shadow masks
turned out to be straightforward using this technique, suggesting its potential utility in preparing designer sensor
structures using functionalized nanoparticles.
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Quality of diamond films is strongly dependent on substrate temperatures, which are usually controlled in a range of 600
- 1100 °C in most experiments. Although many applications have been achieved with these techniques, diamond film
growth is still not possible for substrates that cannot endure such high temperatures for long time. In this study, a
continue-wave (CW) CO2 laser was used to irradiate the growth area on tungsten carbide (WC) substrates during
C2H2/O2 combustion-flame deposition in order to maintain required temperature in the growth area while keep the rest of
the substrates at a low temperature. The laser power was adjusted between 200 - 600 W to study the effects of laser
irradiation on diamond deposition. Surface morphologies of the deposited films were examined by a scanning electron
microscope (SEM). Film structures were characterized by Raman spectroscopy. It was concluded that the CO2 laser
irradiation during combustion-flame deposition could raise the temperature at the growth area efficiently. Both laser
power and power density have effects on the diamond deposition. Laser irradiation with proper parameters could
improve the crystal quality of the diamond films. Based on the experimental results, the CO2 laser-assisted combustion-flame
deposition is a promising method for local substrate heating during diamond film growth.
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A KrF excimer laser was used in combination with a combustion flame to deposit diamond films on cemented tungsten
carbide (WC-Co) substrates. The laser has a wavelength of 248 nm, a pulse width of 23 ns, a pulse energy range of
84~450 mJ, and a repetition rate up to 50 Hz. Using the combustion flame method, diamond films were deposited on the
laser-processed WC-Co substrates for 10 min. The morphologies of the deposited diamond films were examined using a
scanning electron microscopy (SEM). The composition and bonding structures in the deposited films were studied by
energy dispersive X-ray analysis (EDX) and Raman spectroscopy, respectively. The film adhesion was characterized by
scratching a razor across the films. It was found that C composition on WC-Co substrate surfaces was eliminated by the
laser irradiation. As a consequence, diamond nucleation density decreased and diamond grains grew larger in the laser-processed
areas. Based on the experimental results, a film growth mechanism at different deposition temperature ranges
corresponding to pre-deposition laser-surface-treatment effects was proposed.
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This study presents a novel non-contact method, designated as laser induced local material transfer (LILMT), for
patterning carbon nanotube (CNT) emitters on the cathode of a CNT backlight unit (CNT-BLU) under the environment
of the atmosphere and at room temperature. The LILMT method makes possible the manufacturing of large-scale
substrates with a higher resolution than that which can be attained using familiar screen-printing methods. The
preliminary results obtained for the field emissions of square-type and line-type CNT emitters confirm the effectiveness
of the proposed patterning method.
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Selective Laser Melting (SLM) is a generative manufacturing procedure mainly known for the application with metal
powders. From these, metallic structures are produced in a layer-by-layer way. This layer-related procedure is
comparable to the stereolithographic manufacturing of polymer devices. On a base plate, a thin layer of metal powder is
spread. The powder is locally completely melted by the application of a focused laser beam. The base plate is then
lowered by a value defined by the thickness of the metal layer, metal powder is spread again, and the local melting
process is re-initiated. The complete procedure is continued as described, until the device is manufactured in the defined
way. Commercially available metal powder can be used as base material.
In principle, the SLM process should be suitable for the generation of metallic microstructures. The main precondition
for the generation of microstructures by SLM is that the spatial resolution of the laser focus is small and precise enough
to generate microstructure walls of around 100μm thickness in a reproducible way by melting metal powder. The walls
should be gas- and leak-tight.
In this publication, experimental results of the generation of metallic microstructure devices by SLM will be given. The
process will be described in details. Process parameters for the generation of stainless steel devices having wall
thicknesses in the range of about 100μm will be given. Examples for microstructure devices made by SLM will be
shown. The devices can be manufactured in a reproducible way.
Moreover, very first preliminary results on the use of ceramic powder as base material will be presented.
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