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Effects of carbon 1s core excitations on the structure of tetrahedral amorphous carbon films were investigated by
illuminating samples with intense soft X-rays from a synchrotron radiation source in the photon energy range of 240 eV
to 310 eV. The structural changes detected in the X-ray absorption spectra obtained before and after the intense
illumination are characterized by graphitic ordering, similar to the effect of high-energy electron irradiation. The
excitation spectrum for the photo-stimulated structural changes was found to consist of a non-resonant component and a
resonant component peaking at 289 eV close to the 288 eV XAS peak characteristic of ta-C films. The microscopic
mechanisms are discussed for the non-resonant and the resonant effects.
Koji Maeda,Shijin Liang,Yoshihisa Harada,Yoshinori Kitajima,Shik Shin, andYutaka Mera
"Structural change in amorphous carbon on core excitations induced by soft x-ray illumination", Proc. SPIE 6586, Damage to VUV, EUV, and X-ray Optics, 65860C (23 May 2007); https://doi.org/10.1117/12.723791
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Koji Maeda, Shijin Liang, Yoshihisa Harada, Yoshinori Kitajima, Shik Shin, Yutaka Mera, "Structural change in amorphous carbon on core excitations induced by soft x-ray illumination," Proc. SPIE 6586, Damage to VUV, EUV, and X-ray Optics, 65860C (23 May 2007); https://doi.org/10.1117/12.723791