Adriana Báez-Rodríguez, Luis Zamora-Peredo, Octavio Alvarez-Fregoso, Rafael Martinez-Martinez, Lazaro Huerta-Arcos, Ciro Falcony Guajardo, Marco Alvarez-Perez, Manuel García-Hipólito
Journal of Photonics for Energy, Vol. 9, Issue 04, 046001, (December 2019) https://doi.org/10.1117/1.JPE.9.046001
TOPICS: Europium, Ions, Molybdenum, Crystals, Raman spectroscopy, Doping, Luminescence, Temperature metrology, Quantum efficiency, Scanning electron microscopy
MoO3 and MoO3 : Eu3 + films were synthesized by the pyrosol method. X-ray diffraction diffractograms, acquired as a function of the deposition temperature, indicated the orthorhombic crystalline structure for all studied MoO3 films. Photoluminescence (PL) and cathodoluminescence (CL) characteristics of these films were measured as a function of deposition parameters, such as the substrate temperature and the doping content (Eu3 + ions). As the deposition temperature was increased, an increase in the intensity of the PL and CL emissions was observed. Also, a quenching of the PL and CL, as a function of the doping content, was observed. Quantum efficiency measurements showed an average value as high as 54% and a pure red color was perceived. The elemental composition of the films as determined by x-ray photoelectron spectroscopy is reported as well. Additionally, the surface morphology features of the films, as a function of the deposition temperature (by means of scanning electron microscopy and transmission electron microscopy measurements) are exhibited. Moreover, Raman spectroscopy and decay time measurements were performed on some MoO3 : Eu3 + samples.