A large amount of iron and steel artifacts produced in the central European area between 2nd and 14th Centuries is constituted by pattern welded iron-phosphoric iron and steel components. Phosphoric iron is a substitutional alloy, which is obtained by using iron ore from swamps in which decomposition of dead organisms enriches the iron rich soil with phosphorous. The identification of phosphoric iron alloy in ancient artifacts is important for determining their place of origin, production procedure and technological characteristics. A well-established technique for investigating the bulk structure of ancient metallographic artifacts is neutron tomography, using cold neutrons. It provides image-data capable of enhancing differences between phosphorous rich iron and the standard iron areas. However, neutron imaging is costly and complex to implement. Therefore, the exploration of new techniques capable of providing additional data on the nature of alloys would be highly needed. A pilot study addressed to test the applicability of reflectance hyperspectral imaging to the investigation of ancient metallographic artifacts is presented here. So far this technique has been used for diagnostics of polychrome surfaces, but it has never been applied to investigation of metallic surfaces. Hyperspectral imaging in the VIS-NIR range (400-1700 nm) was applied on replicas of a historical object from the archaeological site of Kobilic (Croatia). The same replicas were analyzed also using neutron tomography. Hyperspectral data were elaborated to map the distribution of the different phases on the surface. The comparison of the hyperspectral data with the neutron tomography data-images provided prominent similarities. These preliminary results encourage further investigations on merging these two imaging techniques for novel applications on archeo-metallurgy.
For more than a decade, a number of studies and research projects have been devoted to customize hyperspectral imaging techniques to the specific needs of conservation and applications in museum context. A growing scientific literature definitely demonstrated the effectiveness of reflectance hyperspectral imaging for non-invasive diagnostics and highquality documentation of 2D artworks. Additional published studies tackle the problems of data-processing, with a focus on the development of algorithms and software platforms optimised for visualisation and exploitation of hyperspectral bigdata sets acquired on paintings. This scenario proves that, also in the field of Cultural Heritage (CH), reflectance hyperspectral imaging has nowadays reached the stage of mature technology, and is ready for the transition from the R&D phase to the large-scale applications. In view of that, a novel concept of hyperspectral camera - featuring compactness, lightness and good usability - has been developed by SPECIM, Spectral Imaging Ltd. (Oulu, Finland), a company in manufacturing products for hyperspectral imaging. The camera is proposed as new tool for novel applications in the field of Cultural Heritage. The novelty of this device relies in its reduced dimensions and weight and in its user-friendly interface, which make this camera much more manageable and affordable than conventional hyperspectral instrumentation. The camera operates in the 400-1000nm spectral range and can be mounted on a tripod. It can operate from short-distance (tens of cm) to long distances (tens of meters) with different spatial resolutions. The first release of the prototype underwent a preliminary in-depth experimentation at the IFAC-CNR laboratories. This paper illustrates the feasibility study carried out on the new SPECIM hyperspectral camera, tested under different conditions on laboratory targets and artworks with the specific aim of defining its potentialities and weaknesses in its use in the Cultural Heritage field.
In recent years Hyper-Spectral Imaging (HSI) technologies have become well-established for applications in the field of Cultural Heritage, and in particular for non-invasive analysis and high quality documentation of paintings and other polychrome surfaces. This paper reports on the latest developments of the on-going research at IFAC-CNR, where a new prototype of a high-performance hyper-spectral scanner, operating in the NIR spectral region (900-1700nm range), was designed, assembled and tested. This new NIR scan-head was designed to be mounted on the same mechanical structure used for the earlier IFAC-CNR scanner prototype, which operated in the 400-900nm range. As ultimate goal the whole system would be intended to provide 2D hyper-spectral data on the extended 400-1700nm range, so as to strongly improve the capability of pigment discrimination, and to increase the possibility of visualizing the underlying features of the polychrome surfaces (such as under-drawings, pentimenti, etc.). In the present version, the NIR scan-head operates with a spectral sampling rate of about 2 nm, and a spatial sampling rate of about 9 dots per millimeter. The results of testing and characterization of the new high resolution NIR IFAC-CNR scanner are presented, with a focus on the main technical problems tackled in customizing the new system for the investigation and documentation of paintings.
Hyper-Spectral Imaging (HSI) has emerged in the last decade as one of the most promising technologies for
diagnostics and documentation of polychrome surfaces. Despite the fact that presently HSI is a well-established
technique for non-invasive investigations on paintings, a number of technological issues remain open and are
still topics for on-going studies. In particular, it is known that high spatial resolution is a crucial parameter for
obtaining high quality images, whereas the possibility to identify pictorial materials strictly depends on the
spectral resolution and on the extent of the spectral region investigated. At the same time, by increasing the
sampling rates in both the spatial and spectral dimensions, the size of the data-set will be enlarged and the
acquisition times will be lengthened. As a consequence, a good compromise between the acquisition of highquality
data and their application should always be reached, taking into account the specific purposes of the HSI
application. The above questions are discussed in the present work, which illustrates two applications of the
latest version of a hyperspectral scanner designed at IFAC-CNR for the digitization of artworks. The prototype
has recently been upgraded, with new visualization software as well as mechanical and optical improvements.
This high performance system operates in the 400-1000nm spectral range, with a spectral resolution of about 2-3
nm and a spatial sampling of 0.1 mm over areas of about 1 m2. Three case-studies are presented, which highlight
the importance of both high spatial and high spectral sampling rate in hyperspectral imaging. Two of the
examples reported focus on the full exploitation of the spatial resolution: the first one is a study performed on a
small painting, dated from the eighteenth century and belonging to the Uffizi Gallery in Florence; the second
case-study refers to the valuable "Carrand diptych" (14th century) from the Bargello Museum in Florence. The
last application, instead, shows the crucial importance of a high spectral resolution to identify selected pigments
in the oil-painting "Ritratto di Maffeo Barberini", dated around 1596-1600, which has recently been attributed to
Caravaggio.
Reflectance spectroscopy supplies fundamental information for investigating art objects and diagnosing their state of conservation. Until recently, reflectance spectra could be measured only on samples taken from the art objects. Recent progresses in fiber optics reflectance spectroscopy (FORS) and image spectroscopy (IS) have made it possible, however, to perform non-invasive measurements. Moreover, the two techniques can supply data in large enough quantities as to make the use of sophisticated statistical methods significant for detecting variations due to ageing and degradation. FORS and IS are, in a sense, complementary techniques as the former provides information on single points, while the latter provides 2-D maps from which the reflectance spectrum of each pixel can be displayed. Both FORS and IS were applied in the case study on the Lansdowne version of the Madonna dei fusi (Madonna of the Yarnwinder). In particular, IS was realized by means of a hyper-spectral scanner recently assembled at the "Nello Carrara" Istituto di Fisica Applicata. The characteristics of the scanner are: 0.1 mm spatial sampling over a 1x1 m2 surface and ~1 nm spectral sampling in the wavelength range from 400 nm to 900 nm. The information provided by these two techniques was consistent with what supplied by the non-invasive techniques employed by the other teams participating in the case study, in particular as regards the pigments, the preparatory layer, the binding medium, and the previous restoration works.
In this paper we present some laboratory measurements obtained by a new imaging interferometer. This instrument has been derived from the so called “stationary interferometers,” which do not employ any moving part to optically scan the instrument field-of-view. The device acquires the image of an object superimposed to a fixed (stationary) pattern of autocorrelation functions of the energy coming from each pixel. The interference pattern, constituted by a system of vertical fringes, is scanned by moving the observed target with respect to the imaging device. In order to calibrate the optical-path-difference axis of the raw interferograms, we have executed a set of measurements employing a He-Ne laser source spread by a pair of planar diffusers. The dependence of the optical-path-difference values on the source spectral content has been addressed performing a set of measurements after filtering a 600W halogen lamp with interference filters of 10nm bandwidth. We have described the procedure of pre-processing of the acquired data to retrieve the spectrum of at-sensor radiance (dark signal subtraction, spectral instrument response compensation, effects of vignetting and Fourier transform algorithm). Some hints are given about the use of this instrument from airborne platforms for remote sensing of the Earth.
The fundamental component of a stationary interferometer is a beam-splitter semi-transparent plate that provides phase-delay between the two interfering rays. The phase-delay changes with varying the incident angle of the entering ray, thus producing the entire interference pattern while moving the device over the surface of the observed target. Due to their technical characteristics these interferometers can reliably be adapted for aerospace remote sensing applications. Their ability to produce the interference of the incoming radiation over a broad spectrum of optical wavelength together with the possibility to accommodate the spectral resolution by changing its optical aperture and the sampling step make these instruments interesting for Earth remote sensing. This paper describes the results coming from laboratory experiments and numerical simulations carried out in order to investigate the use of the static interferometers for remote sensing purposes.
This paper reports about a study concerning the application of error bounded encoding to lossy image compression of ancient documents handwritten on parchments. Images are acquired in the RGB color space and previously transformed in the YUV color coordinate system before coding. The coding algorithm, named RLP, considered here is based on a classified DPCM enhanced by a fuzzy clustering initialization and followed by context based statistical modeling and arithmetic coding of prediction residuals that are quantized with user defined odd step sizes to allow rate control with a minimum peak error over the whole image, so as to exactly limit local distortions. Each YUV component is coded separately; after decoding images are transformed back to RGB color space and compared with the originals in order to quantify distortions. A relationship bounding the peak errors in the RGB color space one the peak error is fixed in the YUV color space is derived. An algorithm originally designed for estimating signal-dependent noise parameters and used to obtain useful information about the images of the documents is also reported in the paper. The performances of the coding method are superior with respect to conventional DPCM schemes thanks to its flexibility and robustness to changes in type of images. For the compression ratios requested by this application the gain of RLP over JPEG is consistent: nearly 2 dB and 5 dB in PSNR for compression ratios of 10 and 5 respectively.
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