A new algorithm to determine the nitrogen dioxide column density in the atmosphere using the MKIV Brewer
spectrophotometers is proposed. The updated technique minimizes the measurement noise and the contribution
of several natural and instrumental factors that could interfere with the measurement. For that, recent
spectroscopic data are employed in the retrieval and a new set of weighting factors was recalculated taking into
account the instrumental characteristics of a real MKIV Brewer. The algorithm was successfully tested on a set
of synthetic spectra simulated with a radiative transfer code.
Currently there is still low spatial coverage of ground-based instruments measuring UV irradiance (spectral or broad band) and the length of time over which reliable UV observations have been made is mainly around 10 years. Solar spectral irradiance (from 290 to 325 nm at 0.5 nm wavelength step) has been measured at the stations of Rome (41.9°N, 12.5°E, 75 m a.s.l.) and Ispra (45.8°N, 8.6°E, 240 m a.s.l.), by means of Brewer single monocromator spectrophotometer since 1992. In this study a climatological characterization based on the time series of UV index (UVI) is presented. The mean of maximum UV indexes is (7.2±0.2) at Ispra and (8.9±0.4) at Rome under clear sky conditions. Low exposure category (UVI<2) is persistent at Ispra and high exposure category (6
Decreasing trends of total ozone affect mainly solar ultraviolet (UV) levels at ground level with adverse effects on the biosphere.
Highly accurate measurements of solar UV irradiance have become an important issue to assess UV trends. To detect these trends stations with well calibrated instruments, with long-term stability and Quality Assurance (QA)/ Quality Control (QC) carefully followed procedures, are necessary. The Solar Radiometry Observatory of Rome, University “La Sapienza” (city center) is one of the stations regularly measuring UV irradiance in Italy. Measurements of UV spectral (290-325 nm) irradiance started in 1992, using Brewer MKIV 067. Measurements of total irradiance contained in the 280 - 320 nm waveband begun in 2000 with the YES UVB-1 broad-band radiometer. An investigation of the internal temperature dependence of the spectral responsivity to improve the quality of the Brewer UV data was carried out. The study was based on the analysis of responsivity files recorded during the years 2000-2002. Responsivities are provided by specific tests through a set of five 50 W quartz tungsten-halogen lamps, traceable to the standards of the National Institute of Standards and Technology (NIST). The lamp tests allow to measure any changes in the instrument response over time. It was observed that a decrease in the instrument's responsivity resulted from an increase of the internal temperature. A methodology based on a family of responsivity files at different temperature intervals is proposed to allow correction of UV irradiances using the responsivity file at the corresponding temperatures. The mean percentage differnce between temperature corrected and non-corrected Brewer data varies from 0.8% to 1.5% over an internal temperature of 8°C-42°C. In addition the results of a field evaluation in Rome between Brewer 067 and two temperature stabilized instruments, a broad-band radiometer (YES UVB-1) and a moderate bandwidth multichannel radiometer (Biospherical GUV-511C) were analyzed using temperature corrected spectral measurements.
An episode of low ozone values over Central Europe on November 29 2000 was observed at some Italian Brewer stations. Middle latitudes ozone variability, at time scales of 1-3 days, depends mainly on the atmospheric motions transport. This paper reports an investigation on synoptic scale ozone components, based on the O3 tendency equations for determining the dynamic cause of the episode. Ultraviolet (UV) irradiance variations are also analyzed in order to find out how the weather patterns may lead to enhanced levels of UV radiation within few days.
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