Hafnia, a main optical material in high-energy laser applications, faces limitations due to precursors prone to laser damage. Addressing these precursors is critical to producing laser-resistant films. Nanobubbles within hafnia layers contribute to laser damage upon UV, nanosecond-laser exposure. This study examines hafnia film deposited by ion beam sputtering with different working gases, either Argon or Xenon. The effect of nanobubble size, which varies according to the working gas used, on the film performance under nanosecond-laser irradiation was investigated. The results indicate that the different nanobubble sizes influenced by the working gas affect the laser damage mechanism.
High reflector coatings are typically constructed of quarter-wave optical thickness (QWOT) multi-layers of alternating high and low refractive index materials. An absentee half-wave optical thickness (HWOT) low refractive index layer, usually SiO2, is typically used for the outermost layer of the coating to improve laser damage resistance. Out of plane oblique angle mirrors typically have an additional polarization retardation minimization requirement to maintain the polarization purity of the laser. For monochromatic lasers with a small angular incident range, this can be accomplished with precise layer thickness control for proper angular centration of the coating because of the narrow angular range for low polarization retardation. Reducing the SiO2 overcoat thickness from HWOT to QWOT significantly increases the spectral bandwidth or angular range for low polarization retardation, however, the standingwave electric field is significantly increased, leading to lower laser resistance. The reflectivity is also reduced leading to the need for extra layers. A three-material hybrid QWOT coating design, with a high fluence medium refractive index material, can be fabricated with simultaneous high laser damage resistance and low phase retardation over a moderately wide spectral or angular range. Finite -difference time-domain simulations explore the impact of different size nodular defects on light intensification in each of the different coating materials for this hybrid design approach. A 2-5x increase in LIDT occurred, depending on polarization, for the two wide low retardation coating, with the best LIDT performance occurring for the narrow low retardation coating.
This year’s laser damage competition involves short pulse laser damage on high reflectors tuned for near normal incidence and >99.5% reflectance for 1030 nm. All laser damage testing was done by Lidaris Ltd. via a near Gaussian laser beam from a commercial laser system (Yb:KGW, Kerr lens mode-lock) operating at 500 kHz repetition rate with 200-fs pulse duration (FWHM). All testing was done in a similar fashion to the ISO 21254-1 and 21254-2 S-on-1 standards, yielding data on laser damage for 10x number of shots, where x = 0, 1, 2, 3, 4, 5, 6. Laser-matter interaction either leads to material removal and ablation or a more subtle coating admittance change. The former is referred to as catastrophic damage while the latter is referred to as color change. The choice of coating materials, design, and deposition method were left to the participants. A double-blind test assured sample and submitter anonymity. The damage performance results (LIDT), sample rankings, details of the deposition processes, coating materials and substrate cleaning methods are shared. These results are compared both to the nanosecond 1053-nm laser damage testing on high reflectors from the 2018 competition as well as the nanosecond-femtosecond damage testing study from the 2020-2021 years. All samples exhibited a fatiguing effect in the laser damage performance at high number of shots, but this was particularly noticeable for the color change damage type. We found that ion beam sputtered HfO2/SiO2 multilayer coatings of approximately 30 total layers did the best for the short pulse regime. This is in sharp contrast to the 1053-nm nanosecond study, which has demonstrated that electron beam deposited HfO2/SiO2 high reflectors are the clear winners.
We present experimental results that show how diode-pumped Tm:YLF can be used to develop the next generation of lasers with high peak and high average power. We demonstrate the production of broad bandwidth, λ≈ 1.9 μm wavelength, high energy pulses with up to 1.6 J output energy and subsequent compression to sub-300 fs duration. This was achieved using a single 8-pass amplifier to boost stretched approximately 50 μJ pulses to the Joule-level. Furthermore, we show the average power capability of this material in a helium gas-cooled amplifier head, achieving a heat removal rate almost ten times higher than the state-of-the-art, surpassing 20 W/cm2. These demonstrations illustrate the capabilities of directly diode-pumped Tm:YLF to support TW to PW-class lasers at kW average power.
We will present our recent advances in identifying, understanding, and suppressing ns laser damage precursors in IBS produced dielectric films under UV, pulsed laser exposure. Model systems of single layer, layer pairs, and MLD coatings of silica, hafnia, scandia, and alumina were investigated. Through materials characterization, laser damage testing and simulations, we revealed that entrapped nanobubbles were important low fluence laser damage precursors. We further demonstrated that the identified precursors could be suppressed by either post low pressure thermal annealing or the manipulation of deposition process including using different sputtering gases to achieve ns UV-laser damage resistant dielectric coatings.
We compare the 355 nm, 45º AOI p-pol 8 n-s laser damage performance of standing-wave hafnia single layers fabricated using argon and xenon as working gas. A suite of metrology tools has been employed to understand the structural, chemical and paramagnetic defect states in the two films. The resultant films from the xenon deposition process are highly dense and have high 3w laser damage performance.
It is well known that dielectric coatings used in high energy laser systems for beam steering are susceptible to laser damage. The laser damage ensued in high refractive index materials, such as hafnia, is responsible for limiting the laser operation fluence and lifetime. Although hafnia is an ideal high refractive index material used in dielectric coatings for a broad range of laser wavelengths, defects developed during the deposition process leads to laser-induced damage. In order to increase the resistance to laser damage and improve laser performance, it is imperative to understand the underlying physics of laser damage in high index coating materials. Earlier work observed a substantial difference in laser damage thresholds for hafnia coatings produced by different deposition methods, yet the underlying mechanisms for the observed difference remains elusive. In this work we investigated the responses of single layer hafnia films produced by two deposition processes, electron beam (e-beam) evaporation and ion beam sputtering (IBS) methods upon UV ns-laser exposure. The films underwent laser damage testing using a 1-on-1 laser damage testing protocol with a beam size of 650 µm (1/e2) at 355 nm and 8 ns pulse duration. Both S and P polarizations were tested at a 45° angle of incidence. Chemical, structural and morphological characterizations of the films both pre- and post-laser damage were performed using Rutherford backscattering spectroscopy, glancing incidence X-Ray diffraction, and optical and scanning/transmission electron microscopy. We found that films deposited from the e-beam process had a higher damage onset threshold (4.4 +/- 0.1 J/cm2) than those deposited by IBS method (2.1 +/- 0.2 J/cm2). Furthermore, a polarization-dependent damage threshold onset was observed for the e-beam evaporated coatings but was not observed in IBS films. Although the typical size of the damage in general is larger for the e-beam produced films, the morphology shows similar foamy appearance in both films. The density of the damage sites, on the other hand, was much greater in the IBS produced films than that by the e-beam method. The observed difference can be attributed to their resulting structural/textural differences inherited in each method: porous in the e-beam films and dense with isolated nanobubbles in the IBS films, which can lead to a large difference in laser-defect coupling. The underlying physical mechanism will be discussed in detail.
This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. IM Release# LLNL-ABS-809117
We compare the 355 nm, 45º AOI p-pol 8 n-s laser damage performance of standing-wave hafnia single layers fabricated under the same conditions and annealed under different temperatures. An intriguing trend is observed in the laser damage performance with respect to annealing temperature, with a notable performance increase observed in the sample annealed at 250º C. Chemical compositional analysis via Rutherford Backscatter spectroscopy (RBS) indicates that annealing induces sub-stoichiometric hafnia films for high temperature annealing.
We compare the distribution of hafnia chemistries as a function of sun and planet position in an ion beam sputtering system. Hafnia film chemistries were investigated both without and with planetary rotation. In the former case, the film thickness, stoichiometries and entrapped argon varied drastically as a function of sun position, with one sun position exhibiting high entrapped argon content. With full planetary rotation used during deposition, the film stoichiometry is nearly ideal with 6% entrapped argon content. It is observed that the center of the planets is an exception, with a slightly metallic stoichiometry and high entrapped argon. Interestingly, all hafnia optical films produced in this study exhibit an inverse relationship between oxygen content and entrapped argon.
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