We introduce a nano-optical platform based on Bloch surface waves (BSWs) capable of exploiting the entire cleaved end facet of a multicore optical fiber. Interconnecting various fiber cores with BSWs directly at the end of a multicore fiber opens the perspective of highly compact complex optical functionalities for the design of “lab on fiber” devices. In counterpart, optical fibers provide a unique opportunity to obtain turnkey nano-optical functions addressing a vast application domain ranging from telecommunications to medical sensing. To show the full potential of our platform, we demonstrate a multiplexing function between three fiber cores.
We introduce a nano-optical platform based on Bloch surface waves (BSWs) capable of exploiting the entire cleaved end facet of a multicore optical fiber. Interconnecting various fiber cores with BSWs directly at the end of a multicore fiber opens the perspective of highly compact complex optical functionalities for the design of “lab on fiber” devices. In counterpart, optical fibers provide a unique opportunity to obtain turnkey nano-optical functions addressing a vast application domain ranging from telecommunications to medical sensing. To show the full potential of our platform, we demonstrate a multiplexing function between three fiber cores.
In recent years, the ability to pattern large areas at the micro- and nano-scale with stimuli-responsive materials has opened the opportunity to engineer surface structures and trigger peculiar properties such as complex optical functionalities or surface properties by laser-matter interactions. The use of light-sensitive materials, such as azobenzene compounds, can open the opportunity to active manipulate in terms of morphology, physical and mechanical properties a pre-patterned architectures, which are intrinsically static once fabricated.
We employ azopolymers, in which the rapid and reversible photoisomerization reaction of azobenzene molecules can actuate mass transport phenomena typically parallel to the light polarization. The azopolymeric film is patterned by soft-imprinting as an array of micro-holes showing a well-defined isotropic round pores. Upon a linearly polarized illumination (365 nm, 150 W/cm2), we observe a deformation of the initial holes along the polarization direction, in such a way that the circular pores are transformed into long closed slits. A rotation of the polarization by 90° triggers a reconfiguration of the pristine round shape, with a good degree of control of the photo-induced pore reshaping. Due to the polarized-directionality of the photo-manipulation we demonstrate the possibility to tune the pristine morphology and properties along specific directions, providing a smart engineered platform with different reshaped micro-patterns. The light-induced contraction and expansion reshaping strategy of a porous polymeric structures shows exciting potential for a number of applications including microfluidics, lithography and tissue engineering. Tuning cells behavior in response to material manipulation cues is a promising goal in biology
In this work we investigate new degrees of freedom in controlling the physical properties of structured photo-sensitive materials that can be usefully exploited in many application fields. We employ azopolymers, a class of light responsive materials, which are structured in micro-pillar array. A reversible and controlled change in morphology of a pre-patterned polymeric film under properly polarized illumination is demonstrated to provide the opportunity to engineer surface structures and dynamically tune their properties. We exploit the laser process taking advantage of the light-induced deformation of a micro-textured azopolymeric film in order to modify the surface hydrophobicity along specific direction.
We propose a liquid polymeric compound based on photo-responsive azo-polymers to be used as light-activated optical element with tunable and reversible functionalities. The interaction of a laser beam locally modifies the liquid density thus producing a refractive index gradient. The laser induced refractive index profiles are observed along the optical axis of the microscope to evaluate the total phase shift induced and along the orthogonal direction to provide the axial distribution of the refractive index variation. The focusing and imaging properties of the liquid lenses as functions of the light intensity are illustrated.
Optical sensors exploiting Bloch surface waves at the truncation edge of one dimensional photonic crystals are used here as a valid alternative to surface plasmon resonance operating in the Kretschmann-Raether configuration, and commonly adopted for label-free optical biosensing. In order to reduce the Bloch surface waves resonance width and increase the resolution it is desirable to work with one dimensional photonic crystals with as small losses as possible. However this makes that the resonances observed in a single polarization reflection scheme are shallow and difficult to track in a sensing experiment. Here we report on the practical implementation of an angularly resolved ellipsometric optical sensing scheme based on Bloch surface waves sustained by tantalia/silica multilayers. The angular resolution is obtained by a focused illumination at fixed wavelength and detecting the angular reflectance spectrum by means of a CMOS array detector. The experimental results, obtained by using one tantalia/silica multilayer with a defined structure, show that the limit of detection can be pushed below 2.1x10-7RIU/Hz1/2.
The misfolding and aggregation of amyloid proteins has been associated with incurable diseases such as Alzheimer's or Parkinson's disease. In the specific case of Alzheimer's disease, recent studies have shown that cell toxicity is caused by soluble oligomeric forms of aggregates appearing in the early stages of aggregation, rather than by insoluble fibrils. Research on new strategies of diagnosis is imperative to detect the disease prior to the onset of clinical symptoms. Here, we propose the use of an optical method for protein aggregation dynamic studies using a Bloch surface wave based approach. A one dimension photonic crystal made of a periodic stack of silicon oxide and silicon nitride layers is used to excite a Bloch surface wave, which is sensitive to variation of the refractive index of an aqueous solution. The aim is to detect the early dynamic events of protein aggregation and fibrillogenesis of the amyloid-beta peptide Aβ42, which plays a central role in the onset of the Alzheimer’s disease. The detection principle relies on the refractive index changes caused by the depletion of the Aβ42 monomer concentration during oligomerization and fibrillization. We demonstrate the efficacy of the Bloch surface wave approach by monitoring in real-time the first crucial steps of Aβ42 oligomerization.
An alternative method to plasmon techniques for the enhancement, control and detection of fluorescence is proposed.
The role of the metallic layer is played by a silicon-based one-dimensional photonic crystal that can sustain Bloch
surface waves (BSWs), which can be regarded as the dielectric analogue of surface plasmon polaritons (SPPs) for
metals. Throughout the paper we explore the route that leads to an enhanced, directionally-controlled and selfreferencing
fluorescence-detection scheme. We first consider a 1DPC that is functionalized with a thin, flat and
homogeneous polymeric layer decorated with a fluorescent dye. The enhancement of the BSW-coupled fluorescence
emission is studied against a similar scheme that uses a common thin glass coveslip. An enhancement as large as 560 is
found. We further investigate the BSW coupling of the illuminating laser light into 30-nm thin polymeric waveguides.
Imaging the BSW-coupled emitted fluorescence through the leakage radiation microscopy is used for the purpose. The
possibility of coupling BSWs into nanometric guiding ridges makes feasible the design of a spatially-resolved and
multiplexing fluorescence-detection scheme, which can be most useful for self-referencing in the biosensing field. We
conclude the paper by investigating the effects on the fluorescence emission of a multistack that consists of a dielectric
multilayer and a thin metallic layer deposited on top. The implications of using a metallo-dielectric structure for the
coupling of the emitted fluorescence with BSW and SPP modes is discussed.
The Rhodamine 6G fluorescence enhanced by the surface electromagnetic waves coupled on surface of 1D
photonic crystals is studied. The fluorescence-mediated surface electromagnetic waves (SEW) distribution
is visualized by means of far-field fluorescence microscopy. The kinetics of Rhodamine 6G bleaching due to
SEW is studied. The way of SEW visualization in reflectivity spectra via fluorescence process is shown. The
prospective for SEW application in the optical sensors field is tested via direct spectroscopy of the photonic
crystal covered by the ethanol and R6G thin film. Spectral flexibility of the SEW excitation depending
on the effective photonic crystal dispersion controlled by its design rather than on material dispersion opens
prospectives for the application of SEW-enhanced fluorescence microscopy in biocensing with increased spatial
and concentration sensitivity and spectral selectivity.
KEYWORDS: Metals, Near field scanning optical microscopy, Near field, Near field optics, Polarization, Coating, Liquid crystals, Aluminum, Quartz, Radio propagation
Fully-metal-coated near-field optical probes, based on a cantilever design, have been studied theoretically and experimentally. Numerical simulations prove that these structures allow non-zero modal emission of the electromagnetic field trough a 60 nm thick metallic layer, that is opaque when deposited on flat substrates. The far-field intensity patterns recorded experimentally correspond to the ones calculated for the fundamental and first excited LP modes. Moreover, this study demonstrates that a high confinement of the electromagnetic energy can be reached in the near-field, when illuminated with radially polarized light. Finally, it was verified that the confinement of the field depends on the volume of the probe apex. The coupling and transmission of transverse and longitudinal fields into the probes has been also investigated. Two kinds of probes with different metal coating roughness are considered. Transverse and longitudinal field distributions are obtained by focusing azimuthally and radially polarized beams produced by means of a liquid crystal plate. The focal plane is scanned using microfabricated probes in a collection mode configuration. It is found that the roughness of the metal coating plays an important role in the coupling strength of transverse fields into the probes: the relative coupling efficiency for transverse fields diminishes with a rough metal coating, while that of longitudinal fields does not.
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