Whispering Gallery Mode (WGM) microlasers were obtained by impregnating polystyrene microspheres in an aqueous solution of plasmonic nanoparticles and Rhodamine 6G. The emission spectra of Rhodamine-doped microspheres with diameters of 1 μm and 5-7 μm exhibited peaks corresponding to WGM, with a low Q-factor for 1-μm and a higher Q-factor for 5-7-μm spheres. The embedding of gold nanoparticles into microlasers results in a 40% decrease in the WGM intensity, while doping with silver nanoparticles increases it by 10%.
An anisotropic Ag@Au nanostructure is fabricated via physical vapor deposition of gold at oblique incidence onto a glass substrate with a preformed silver nanoparticle array. Utilization of silver nanoparticles as a scaffold for subsequent gold deposition makes it possible to control the size and shape of the gold capping layer. The obtained Ag@Au nanostructures are characterized by adjustable absorption bands and linear dichroism. The proposed technique provides for new opportunities in creation of plasmonic nanoparticles with targeted optical characteristics for applications in nanophotonics.
The hybrid nanomaterials based on inorganic matrix and organic compound with customizable properties have practical potential in the field of new developments in biological and chemical sensors, photonic and solar cell devices, as well as laser media. The optical properties of molecular clusters so called J-aggregates embedded in nanoporous aluminum oxide in presence of silver plasmonic nanoparticles were studied. The unique technique for obtaining nanoporous aluminum oxide on the island silver film was proposed. The optimal parameters of the impregnation of nanopores in the ethanol solution of pseudoisocyanine dye for the J-aggregate formation have been studied. The resonant transfer of optical energy from the oxygen vacancy in aluminum oxide to organic molecules was observed in the resulting hybrid films.
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