Unique spectroscopic properties of isolated rare earth ions in solids offer optical linewidths rivaling those of trapped
single atoms and enable a variety of recent applications. We design rare-earth-doped crystals, ceramics, and fibers with
persistent or transient "spectral hole" recording properties for applications including high-bandwidth optical signal
processing where light and our solids replace the high-bandwidth portion of the electronics; quantum cryptography and
information science including the goal of storage and recall of single photons; and medical imaging technology for the
700-900 nm therapeutic window. Ease of optically manipulating rare-earth ions in solids enables capturing complex
spectral information in 105 to 108 frequency bins. Combining spatial holography and spectral hole burning provides a capability for processing high-bandwidth RF and optical signals with sub-MHz spectral resolution and bandwidths of
tens to hundreds of GHz for applications including range-Doppler radar and high bandwidth RF spectral analysis.
Simply stated, one can think of these crystals as holographic recording media capable of distinguishing up to 108
different colors. Ultra-narrow spectral holes also serve as a vibration-insensitive sub-kHz frequency reference for laser
frequency stabilization to a part in 1013 over tens of milliseconds. The unusual properties and applications of spectral
hole burning of rare earth ions in optical materials are reviewed. Experimental results on the promising Tm3+:LiNbO3 material system are presented and discussed for medical imaging applications. Finally, a new application of these
materials as dynamic optical filters for laser noise suppression is discussed along with experimental demonstrations and
theoretical modeling of the process.
We introduce new figures of merit (FOM's) for resonant optical materials used in recording, storage, and
processing of optically encoded information using coherent optical transients. The goal is to account for maximum
coherence storage time as well as for efficiency of the light matter interaction quantified using the ratio between
the rate of dephasing and the rate of spontaneous radiative decay. Highest FOM values are achieved when the
dephasing rate approaches the fundamental limit set by spontaneous emission under the condition that the total
transition oscillator strength is concentrated between a single pair of energy levels. In this case, the information
(both classical and quantum) can be transferred from the radiation field to the storage medium and back at the
fastest possible rate, while the loss of optically prepared coherence is minimized. We analyze FOM's of some of
the most promising rare-earth-doped crystals at cryogenic temperatures and show that the homogeneous line width
may approach the radiative limit in some cases even when the peak cross section remains below the fundamental
limit.
Spatial-spectral holography using spectral hole burning materials is a powerful technique for performing real-time, wide-bandwidth information storage and signal processing. For operation in the important 1.5 μm communication band, the material Er3+:Y2SiO5 enables applications such as laser frequency stabilization, all-optical correlators, analog signal processing, and data storage. Site-selective absorption and emission spectroscopy identified spectral hole burning transitions and excited state T1 lifetimes in the 1.5 μm spectral region. The effects of crystal temperature, Er3+-dopant concentration, magnetic field strength, and crystal orientation on spectral diffusion were explored using stimulated photon echo spectroscopy, which is the "prototype" interaction mechanism for device applications. The performance of Er3+:Y2SiO5 and related Er3+ materials has been dramatically enhanced by reducing the effect of spectral diffusion on the coherence lifetime T2 through fundamental material design coupled with the application of an external magnetic field oriented along specific directions. A preferred magnetic field orientation that maximized T2 by minimizing the effects of spectral diffusion was determined using the results of angle-dependent Zeeman spectroscopy. The observed linewidth broadening due to spectral diffusion was successfully modeled by considering the effect of one-phonon (direct) processes on Er3+ - Er3+ interactions. The reported studies improved our understanding of Er3+ materials, explored the range of conditions and material parameters required to optimize performance for specific applications, and enabled measurement of the narrowest optical resonance ever observed in a solid-with a homogeneous linewidth of 73 Hz. With the optimized materials and operating conditions, photon echoes were observed up to temperatures of 5 K, enabling 0.5 GHz bandwidth optical signal processing at 4.2 K and providing the possibility for operation with a closed-cycle cryocooler.
Single-frequency diode lasers have been frequency stabilized to 200 Hz at 1.5 microns and to 20 Hz at 793 nm with 10-100 ms integration times using narrow spectral holes in the absorption lines of Er3+ and Tm3+ doped cryogenic crystals. The narrow spectral holes are used as frequency references, and this laser performance was obtained without requiring vibrational isolation of either the laser or frequency reference. Kilohertz frequency stability for 100 s integration times is provided by these techniques, and that performance should be improved to the Hertz level and should be extended to longer integration times with further development. Miniaturized external cavity diode lasers and 5 mm-sized reference crystals will provide compact portable packages with a closed cycle cryocooler. The achieved frequency stabilization provides lasers that are ideal for interferometry, high-resolution spectroscopy such as photon echoes, real time optical signal processing based on spectral holography, and other applications requiring ultranarrow-band light sources or coherent detection.
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.