Highly transparent polycrystalline lanthanum-modified lead zirconate titanate (PLZT) thick films were prepared using
aerosol deposition method (ADM) of calcined complex powders. Effects of incident angle of aerosol and particle size as
well as annealing temperature on optical and electro-optic properties of films were investigated. The film with higher
transparency was obtained with smaller particle, because the aggregation frequency of particles in aerosol decreased with
reducing the particle size. The transparency of the films increased with decreasing the incident angle of aerosol. This is
presumably due to the fact that the optimal incident angle of aerosol results in the reduction of impurity and pore, which
makes the film to be denser micro-structurally. The XRD peaks of as-deposed films shifted to lower angle side,
indicating that large compressive stress, which was generated by mechanical collision of particles, acted in the films. But
the stress was eliminated through annealing process. The birefringence change in annealed film increased exponentially
with an applied electrical field to reach 0.0036 at 100kV/cm. To make a multimode waveguide, the PLZT film with 22
μm thick was formed into a silicon groove, which was fabricated through anisotropic wet etching process. The far field
profile of multimode optical wave transmitted through the fabricated PLZT waveguide was successfully observed and
could be controlled with an applied electrical field.
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