The hot carrier dynamics of thermally stable triple halide perovskite solar cells are investigated through power dependent transient absorption (TA) measurements. The TA measurements from both front and back sides of the solar cells were done to better understand the cooling processes. After extracting the PV parameters of the solar cells from the J-V characteristics, the TA measurements were repeated in-operando conditions and under varying external biases to monitor the thermalization of the carriers in more practical conditions.
The 2D Ruddlesden- Popper perovskite (EPEA)2PbI4 was investigated using temperature - and power -dependent PL and TA spectroscopy. This endeavor revealed the presence of multiple excitonic complexes in these materials, with signatures of carrier redistribution mediated by power and/or temperature, and the presence of extremely long-lived dark states in TA. These states appear to be light -induced defects which heal after illumination ceases. As such, they bring new insight into failure mechanisms and material design approaches in perovskite photovoltaics
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.