Interlayer triplet energy transfer in Dion-Jacobson 2-dimensional lead halide perovskites containing naphthalene-diammonium cations

YunHui L. Lin; Justin C. Johnson

doi:10.1117/12.2594289

1 August 2021 Interlayer triplet energy transfer in Dion-Jacobson 2-dimensional lead halide perovskites containing naphthalene-diammonium cations

YunHui L. Lin, Justin C. Johnson

Author Affiliations +

Proceedings Volume 11799, Physical Chemistry of Semiconductor Materials and Interfaces XX; 117990Q (2021) https://doi.org/10.1117/12.2594289
Event: SPIE Nanoscience + Engineering, 2021, San Diego, California, United States

Abstract

While interlayer triplet energy transfer has been studied in Ruddlesden-Popper 2D perovskites containing monovalent naphthalene cations, the photophysical properties of their Dion-Jacobson analogue have not been reported. Here we examine interlayer energy transfer in a series of mixed-halide Dion-Jacobson 2D perovskites containing divalent naphthalene cations. We find that sensitized phosphorescence in these compounds is dominated by naphthalene triplet excimer emission, but when the lead halide exciton is tuned near resonance with the triplet of naphthalene, emission from the naphthalene triplet monomer competes with triplet excimer formation. Interlayer energy transfer in these compounds is further supported by ultrafast transient absorption spectroscopy.

Conference Presentation

Citation Download Citation

YunHui L. Lin and Justin C. Johnson "Interlayer triplet energy transfer in Dion-Jacobson 2-dimensional lead halide perovskites containing naphthalene-diammonium cations", Proc. SPIE 11799, Physical Chemistry of Semiconductor Materials and Interfaces XX, 117990Q (1 August 2021); https://doi.org/10.1117/12.2594289

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available