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Under photochemical reaction the critical wavelength A o absorbed is different for different kind of molecule. And it varies with molecular excited state and environmental temperature T, and so on. Owing to the radiation wavelength A of free electron laser is tunable, therefore its applied range and quantum yield satisfied us.
Han Han
"The photochemical effect and application on free electron laser", Proc. SPIE 1230, International Conference on Optoelectronic Science and Engineering '90, 12303Z (1 July 1990); https://doi.org/10.1117/12.2294780
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Han Han, "The photochemical effect and application on free electron laser," Proc. SPIE 1230, International Conference on Optoelectronic Science and Engineering '90, 12303Z (1 July 1990); https://doi.org/10.1117/12.2294780