Temperature dependence of the C1+HN3 reaction from 300 to 480 K

Gerald C. Manke II; Thomas L. Henshaw; Timothy J. Madden; Gordon D. Hager

doi:10.1117/12.384267

4 May 2000 Temperature dependence of the C1+HN₃ reaction from 300 to 480 K

Gerald C. Manke II, Thomas L. Henshaw, Timothy J. Madden, Gordon D. Hager

Proceedings Volume 3931, Gas, Chemical, and Electrical Lasers and Intense Beam Control and Applications; (2000) https://doi.org/10.1117/12.384267
Event: Symposium on High-Power Lasers and Applications, 2000, San Jose, CA, United States

Abstract

The rate constant for Cl + HN₃ over the temperature range 300-480 K has been studied in a flow reactor. Based on the rate of loss of HN₃ and the rate of NCL(a₁(Delta) ) generation, the temperature dependence of this reaction is described by the collision theory expression 1.2 +/- 0.3 X 10^-11 T^0.5 exp(-1514 +/- 93/T), with E₀ equals 3.0 +/- 0.2 kcal mol^-1 or an Arrhenius fit k(T) equals 2.0 +/- 1.0 X 10^-10 exp(-1452 +/- 150/T) with E_a equals 2.9 +/- 0.2 kcal mol^-1.

Citation Download Citation

Gerald C. Manke II, Thomas L. Henshaw, Timothy J. Madden, and Gordon D. Hager "Temperature dependence of the C1+HN₃ reaction from 300 to 480 K", Proc. SPIE 3931, Gas, Chemical, and Electrical Lasers and Intense Beam Control and Applications, (4 May 2000); https://doi.org/10.1117/12.384267

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