Microwave assisted chemical vapour deposited bulk diamond products have been used in a range of high power laser systems, due to low absorption across a range of wavelengths and exceptional thermal properties. However the application of polycrystalline products has frequently been limited to applications at longer wavelengths or thermal uses outside of the optical path due to the birefringence and scatter that are intrinsic properties of the polycrystalline materials. However, there are some solid state structures, including thin disc gain modules and amplifiers, that will gain significantly in terms of potential output powers if diamond could be used as a heat spreader in the optical path as well as a heat spreader on the rear surface of the disk. Therefore single crystal grades of diamond have been developed that overcome the limitations of the polycrystalline material, with low absorption, low scatter and low birefringence grades for demanding optical applications. We will present new data, characterising the performance of these materials across infra-red and visible wavelengths with absorption coefficient measured by laser calorimetry at a range of wavelengths from 1064 nm to 452 nm.
Infrared absorption of high-quality, commercial, polycrystalline MgAl 2 O 4 spinel is ∼40% greater in the range of 3.8 to 5.0 μm than the value predicted by the computer code OPTIMATR®, which has been used for window and dome design for more than 20 years. As a result, spinel and a -plane sapphire windows designed to support the same external pressure with the same probability of survival have approximately the same infrared absorptance in the range 3.8 to 5.0 μm. c -Plane sapphire has greater absorptance than spinel in the range 3.8 to 5.0 μm. Spinel has two weak absorption bands near 1.8 and 3.0 μm. At 1.064 μm, the laser calorimetric absorption coefficient of spinel is 10 to 50 times greater than that of sapphire. New measurements of specific heat capacity, thermal expansion, thermal conductivity, elastic constants, and refractive index (including dn/dT ) of spinel are reported.
Epitaxial single-crystal chemical-vapor-deposited diamond with (100) crystal orientation is obtained from Element Six (Ascot, United Kingdom) and Apollo Diamond (Boston, Massachusetts). Both companies supply 5×5-mm squares with thicknesses of 0.35 to 1.74 mm. Element Six also provides disks with a state of the art diameter of 10 to 11 mm and a thickness of 1.0 mm. The absorption coefficient measured by laser calorimetry at 1.064 µm is 0.003 cm−1 for squares from Element Six and 0.07 cm−1 for squares from Apollo. One Apollo specimen has an absorption coefficient near those of the Element Six material. Absorption coefficients of Element Six disks are 0.008 to 0.03 cm−1. Each square specimen can be rotated between orientations that produce minimum or maximum loss of polarization of a 1.064-µm laser beam transmitted through the diamond. Minimum loss is in the range 0 to 11% (mean=5%) and maximum loss is 8 to 27% (mean=17%). Element Six disks produce a loss of polarization in the range 0 to 4%, depending on the angle of rotation of the disk. Part of the 0.04 to 0.6% total integrated optical scatter in the forward hemisphere at 1.064 µm can be attributed to surface roughness.
Epitaxial single-crystal chemical-vapor-deposited diamond was obtained from Element Six Ltd. (Ascot, UK) and from
Apollo Diamond (Boston, MA). Both companies provided 5 x 5 mm squares with thicknesses ranging from 0.5 to 1.5
mm. In addition, Element Six provided 10-mm-diameter disks with a thickness of 1.0 mm. The absorptance of all
specimens at 1064 nm was measured by laser calorimetry, with good agreement between independent measurements at
the University of Central Florida and at QinetiQ (Malvern, UK). Depolarization at 1064 nm and ultraviolet absorption
properties are also reported.
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.