Localized surface plasmon resonance (LSPR) of noble metal nanoparticles is an optical phenomenon to enhance the electro-magnetic field near a particle and has the potential to enhance the performance of solid-state triplet-triplet annihilation photon upconversion (TTA-UC). In order to fully utilize an enhanced electro-magnetic field generated by LSPR, the spatial arrangement of dye molecules near noble metal nanoparticle plays an important role. In this study, donor and acceptor molecules are sequentially introduced on the plasmonic nanoparticles and investigated the correlation between the spatial arrangement of dye molecules and the UC enhancement behavior in solid-state TTA-UC.
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