The output of a laser frequency comb is composed of 100,000+ perfectly spaced, discrete wavelength elements or comb teeth, that act as a massively parallel set of single frequency (CW) lasers with highly stable, well-known frequencies. In dual-comb spectroscopy, two such frequency combs are interfered on a single detector yielding absorption information for each individual comb tooth. This approach combines the strengths of both cw laser spectroscopy and broadband spectroscopy providing high spectral resolution and broad optical bandwidths, all with a single-mode, high-brightness laser beam and a simple, single photodetector, detection scheme. Here I will touch on the application of this system for open-path measurements of atmospheric trace gases (CH4, CO2, CO, NH3, water, ethane, and N2O) and volatile organic compounds (acetone, isopropanol, propane) with field applications targeting industrial oil and gas monitoring and agriculture.
Dual-comb spectroscopy has recently attracted significant interest due to its fast acquisition times, absolute frequency accuracy, negligible lineshape, and coherent probe light. We have recently expanded our near-infrared dual-comb spectroscopy efforts to the mid-infrared, which offers significantly improved sensitivity for many trace gas species and access to other species which cannot be measured in the Near-Infrared.
Our Mid-Infrared spectrometer is based on two erbium fiber optical frequency combs that generate light spanning from about 3 to 5 microns using a two-branch difference frequency generation (DFG) design with a periodically poled lithium niobate crystal (PPLN). The data product of the spectrometer are interferograms. Once digitized, the interferograms are corrected for residual phase noise of the frequency combs and coadded in real-time on a field-programmable gate array (FPGA). Finally, the optical spectrum is calculated through a Fourier transform of the coadded interferogram.
I will present three measurement modalities we implemented with this spectrometer. In a laboratory gas cell measurement, we characterized low-pressure gas phase propane, demonstrating excellent agreement with literature spectra obtained with high-resolution FTIR. In a separate measurement, we performed in-situ monitoring of a chemical reaction using attenuated total reflection spectroscopy. Finally, open-path measurements of atmospheric trace gases (methane, CO2, water, ethane) and volatile organic compounds (acetone, isopropanol) demonstrate the spectrometer's capability to monitor atmospheric trace gases and quantify emissions from sources like oil and gas, forest fires and industry.
The output of a laser frequency comb is composed of 100,000+ perfectly spaced, discrete wavelength elements or comb teeth, that act as a massively parallel set of single frequency (CW) lasers with highly stable, well-known frequencies. In dual-comb spectroscopy, two such frequency combs are interfered on a single detector yielding absorption information for each individual comb tooth. This approach combines the strengths of both cw laser spectroscopy and broadband spectroscopy providing high spectral resolution and broad optical bandwidths, all with a single-mode, high-brightness laser beam and a simple, single photodetector, detection scheme. Here we show that this novel spectroscopy source can be employed for regional (~kilometer squared) monitoring using an array of stationed retros or in conjunction with an unmanned aerial systems (UAS). Both fixed and UAS systems combine the high-precision, multi-species detection capabilities of open-path DCS with the spatial scanning capabilities to enable spatial mapping of atmospheric gas concentrations. The DCS systems measure the atmospheric absorption over long, 100m to 1 km, open air paths with 0.007cm-1 resolution over 1.57 to 1.66 um, covering absorption bands of CO2, CH4, H2O and isotopologues.
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