This PDF file contains the front matter associated with SPIE Proceedings Volume 10331, including the Title Page, Copyright information, Table of Contents, and Conference Committee listing.

Such developments come from conservation experts in the community of cultural heritage - encompassing artworks, museum artifacts or historical monuments - for less intrusive and non-destructive tools to gain information about the subject. Increasingly the demand is for information regarding internal structures and indications of life histories and behaviors of an object. As it is well known, the deterioration due to the capillary rise of water through the walls is a very widespread problem. In this paper, a study of Stimulated Infrared thermography and Evanescent-Field Dielectrometry was applied to a non-destructive mapping, in situ, and in a semi-quantitative way the distribution of water, salt and the structural deterioration induced in a wall of the 13th century of the abbey’s church of Chaalis. Complementarity of the both techniques will be underlined. The Stimulated Infra-Red Thermography (SIRT) is a contact free technique and allows the detection of plaster layers delamination of masonry. Evanescent-Field Dielectrometry (EFD) is a recent diagnostic method based on dielectric spectroscopy at microwave frequency. The measuring instrument is a portable resonant microwave device for mapping the water content and salinity on flat surface up to a depth of 2–3 cm in real time, in a non-destructive way. The method detects the water content and salt concentration in frescoes and walls by estimating the dielectric properties of tested porous materials that is viewed as a “binary” dielectric mixture consisting of bulk material and water, by the contrast between the dielectric constant of a dry material and water. According to the resolution of the optics, the SIRT has a less lateral resolution and more limited in depth, but it is easy to implement and can be used on-site, like in scaffolding conditions. Moreover, this technique gives an overview at a larger scale (metric) than EFD (centimetric).

Interdependence between color and gloss is a concept well-known by artists, especially by old masters, but is not usually considered in material characterization. Indeed, measurement methods and definitions consider these two attributes individually. This research investigates how the available measurement methods for gloss and color (saturation) fit with corresponding perceptual qualities, glossiness and saturation. The definitions of both measured quantities, as well the measurement methodologies, were developed for reference materials (ceramic tiles for color and dark glass specimen for gloss) not representative of artwork materials and do not consider observation conditions similar with those adopted during exhibitions. The prediction of material appearance is recognized as one of the most important challenges in applied metrology, because appearance is the key to achieve effective exhibitions and consumers choices. The results of this study highlight that the two perceived qualities are mutually related, as well the measured quantities: gloss and saturation mutually interfere and the measurement methods and quantities are not uniform with the perceived qualities and the colorimetric coordinate C* no longer describes the perceived saturation.

For more than a decade, a number of studies and research projects have been devoted to customize hyperspectral imaging techniques to the specific needs of conservation and applications in museum context. A growing scientific literature definitely demonstrated the effectiveness of reflectance hyperspectral imaging for non-invasive diagnostics and highquality documentation of 2D artworks. Additional published studies tackle the problems of data-processing, with a focus on the development of algorithms and software platforms optimised for visualisation and exploitation of hyperspectral bigdata sets acquired on paintings. This scenario proves that, also in the field of Cultural Heritage (CH), reflectance hyperspectral imaging has nowadays reached the stage of mature technology, and is ready for the transition from the R&D phase to the large-scale applications. In view of that, a novel concept of hyperspectral camera - featuring compactness, lightness and good usability - has been developed by SPECIM, Spectral Imaging Ltd. (Oulu, Finland), a company in manufacturing products for hyperspectral imaging. The camera is proposed as new tool for novel applications in the field of Cultural Heritage. The novelty of this device relies in its reduced dimensions and weight and in its user-friendly interface, which make this camera much more manageable and affordable than conventional hyperspectral instrumentation. The camera operates in the 400-1000nm spectral range and can be mounted on a tripod. It can operate from short-distance (tens of cm) to long distances (tens of meters) with different spatial resolutions. The first release of the prototype underwent a preliminary in-depth experimentation at the IFAC-CNR laboratories. This paper illustrates the feasibility study carried out on the new SPECIM hyperspectral camera, tested under different conditions on laboratory targets and artworks with the specific aim of defining its potentialities and weaknesses in its use in the Cultural Heritage field.

The application of the thermal and infrared technology in different areas of research is considerably increasing. These applications involve Non-destructive Testing (NDT), Medical analysis (Computer Aid Diagnosis/Detection- CAD), Arts and Archaeology among many others. In the arts and archaeology field, infrared technology provides significant contributions in term of finding defects of possible impaired regions. This has been done through a wide range of different thermographic experiments and infrared methods. The proposed approach here focuses on application of some known factor analysis methods such as standard Non-Negative Matrix Factorization (NMF) optimized by gradient-descent-based multiplicative rules (SNMF1) and standard NMF optimized by Non-negative least squares (NNLS) active-set algorithm (SNMF2) and eigen decomposition approaches such as Principal Component Thermography (PCT), Candid Covariance-Free Incremental Principal Component Thermography (CCIPCT) to obtain the thermal features. On one hand, these methods are usually applied as preprocessing before clustering for the purpose of segmentation of possible defects. On the other hand, a wavelet based data fusion combines the data of each method with PCT to increase the accuracy of the algorithm. The quantitative assessment of these approaches indicates considerable segmentation along with the reasonable computational complexity. It shows the promising performance and demonstrated a confirmation for the outlined properties. In particular, a polychromatic wooden statue and a fresco were analyzed using the above mentioned methods and interesting results were obtained.

For the conservation of cultural monuments standard anti-corrosion coatings are not applicable because the historical character of the objects would be lost. Alternative transparent coatings have to be evaluated and monitored nondestructively with respect to their effectiveness in protecting metal surfaces. We demonstrate that Optical Coherence Tomography (OCT) can be an alternative to the currently used method of Electrochemical Impedance Spectroscopy (EIS) for the characterization of coating defects and corrosion processes.

Surface metrology of artworks requires the design of suitable devices for in-situ non-destructive measurement together with reliable procedures for an effective analysis of such non-engineered variegate objects. To advance the state-of-the-art it has been implemented a versatile optical micro-profilometry taking advantage of the adapt- ability of conoscopic holography sensors, able to operate with irregular shapes and composite materials (diffusive, specular, and polychrome) of artworks. The scanning technique is used to obtain wide field and high spatially resolved areal profilometry. The prototype has a modular scheme based on a set of conoscopic sensors, extending the typical design based on a scanning stage and a single probe with a limited bandwidth, thus allowing the collection of heights data from surface with different scales and materials with variegate optical response. The system was optimized by characterizing the quality of the measurement with the probes triggered in continuous scanning modality. The results obtained on examples of cultural heritage objects (2D paintings, 3D height-relief) and materials (pictorial, metallic) demonstrate the versatility of the implemented device.

Optical diagnostics techniques are becoming important for technical art history (TAH) as well as for heritage conservation. In recent years, optical coherence tomography (OCT) has been increasingly used as a novel technique for the inspection of artwork, revealing the stratigraphy of paintings. It has also shown to be an effective tool for vanish layer inspection. OCT is a contactless and non-destructive technique for microstructural imaging of turbid media, originally developed for medical applications. However current OCT instruments have difficulty in paint layer inspection due to the opacity of most pigments. This paper explores the potential of OCT for the investigation of paintings with coloured grounds. Depth scans were processed to determine the light penetration depth at the optical wavelength based on a 1/e light attenuation calculation. The variation in paint opacity was mapped based on the microstructural images and 3D penetration depth profiles was calculated and related back to the construction of the artwork. By determining the light penetration depth over a range of wavelengths the 3D depth perception of a painting with coloured grounds can be characterized optically.

A high-resolution mobile handheld scanning device suitable for 3D data acquisition and analysis for forensic investigations, rapid prototyping, design, quality management, and archaeology with a measurement volume of approximately 325 mm x 200 mm x 100mm and a lateral object resolution of 170 µm developed at our institute is introduced. The scanners weight is 4.4 kg with an optional color DLSR camera. The PC for measurement control and point calculation is included inside the housing. Power supply is realized by rechargeable batteries. Possible operation time is between 30 and 60 minutes. The object distance is between 400 and 500 mm, and the scan time for one 3D shot may vary between 0.1 and 0.5 seconds. The complete 3D result is obtained a few seconds after starting the scan. For higher quality 3D and color images the scanner is attachable to tripod use. Measurement objects larger than the measurement volume must be acquired partly. The different resulting datasets are merged using a suitable software module. The scanner has been successfully used in various applications.

Digital shearography is a well-established technique for non-destructive testing of composite structures. Furthermore the application for defect detection on artwork could also be successfully proven. While in general the location of a defect in the object plane works very well, no depth information is obtained. To overcome this issue, similar to thermography, the lock-in-technique can be applied to shearography. Due to different modulation frequencies the penetration depth of the thermal wave can be controlled. This enables the determination of depth information. In this paper we investigate the potential of the lock-in-technique for the use in non-destructive testing of artwork. Therefore we do simulations on a wooden panel with different defect-depth. We describe the basic concept and compare the results with lock-in thermography. Finally, we show that the blind-frequency is suitable for quantitative depth information in lock-inshearography and discuss limits, to be overcome.

Several problems of spectral photometry analysis of handwritten documents have been studied like combined reflection from the both ink and paper material impregnated by ink, the illumination spatial non-uniformity with small light intensity, flexibility and instability of paper sheets. The images acquired at different wavelengths were spatially matched using developed computer algorithm and then regions of interests, i.e. ink lines were extracted. Then reflection spectra obtained at all pixels of ink lines were composed in vector representation, and comparison of the vectors was conducted. As the result, degree of correspondence between different fragments of text has been evaluated. The optical setup and its calibration procedures are considered in detail as well as results of image processing, matching, segmentation and spectral photometry evaluation of ink. Experimental results of different text fragments matching and estimates of text fragments spectral correspondence degree are presented and discussed.

The aim of research was determination of composition and nature of superficial deposits, cumulated at the selected mosaic’s tesserae from Lebanon. Selected were three series of objects from different locations, namely from the seaside and mountain archaeological sites as well as from the mosaics exposed in the city center. Analyzed were stone and ceramic tesserae. The selection of objects was dictated by wide diversification of factors influencing the state of preservation and composition of deposits in given location. Investigations were performed including LIBS, FT-IR, Raman spectroscopy and optical 3D microscopy. The experimental results included composition and kind of deposit at the tesserae surfaces, and composition of tesserae itself. Compounds in the superficial deposits were identified. Confirmed was occurrence of different encrustations in dependence on geographic localization of a given sample. The interpretation of results was supported by multivariate statistical techniques, especially by the factor analysis. Performed analyses constitute the pioneer realization in terms of determination of deposits composition at the surface of mosaics from the Lebanon territory.

In the field of Cultural Heritage and conservation science the development of non-invasive tools to retrieve information on artworks and historical artifacts remains one of the most important and increasing demands. In this work a focus was made on the capability of THz imaging to investigate the internal structure of objects made of superposed plaster layers. In particular, a first attempt of investigation was made for gypsum based plaster used for a stucco reliefs. After a feasibility phase on plaster moke up samples, a 15th century painted stucco relief was investigated by means of THz-TDI in the framework of the ESPRIT project, promoted by the Louvre Museum. The objectives were to assess the presence of internal layers made of different plaster mixtures, to locate them and give useful information about the supposed manufacturing techniques. The refractive indexes of different plasters were measured. Due to multiple scattering inside the samples and the impact of the heterogeneity of the material on this refractive index, the interface between plaster/plaster seems difficult to detect.

The characterization of the surface morphology and the material layers stratigraphy is a pivotal step in several stages of the conservation process of the artwork. Generally, optimal characterization of the surface cannot be achieved using a single technique but is not always possible to find techniques that can be coupled effectively. Surface maps were retrieved using acoustic microscopy and conoscopic laser holography over a set of reference samples. The surface maps compared for showing possible way to better characterize the surface morphology when their information is combined. The final data give us a more complete surface and subsurface digitalization while the results obtained are discussed highlighting the main pros and cons of the two techniques. Thus besides having insights on the effectiveness and on the performance of the processes, it is also evident that uncertainties associated with the measurement can be overcome and a single more accurate representation of the surface can be derived using both scanning methods.

Painted caves are a specific environment which preservation needs multidisciplinary studies carried out within the different actors. The actions set-up must follow national and European ethics and treaties and be as less invasive as possible to preserve the integrity of the site. Studying colorants in caves should meet these expectations and take into account on-field conditions: high humidity rate, reduced access to electricity, etc. Therefore, non-invasive analyses should be preferred. However, their limits restrict the field of application and sometimes sampling and laboratory analyses must be used to answer the problematic. It is especially true when the pigment is covered by calcite. For this purpose, the Laser-Induced Breakdown Spectroscopy (LIBS) has been assessed to identify the composition with stratigraphic analyses. This study carries out in-depth profile on laboratory samples in conditions close to the ones meet in caves. Samples were prepared on a calcareous substrate using three pigments: red ochre, manganese black and carbon black and two binding media: water and saliva. All samples have been covered by calcite. Four sets of measurements have then been done using the LIBS instrument. The in-depth profiles were obtained using the Standard Normal Variate (SNV) normalization. For all the samples, the pigment layer was identified in the second or third shot, the calcite layer being quite thin. However, the results remain promising with the carbon black pigment but not really conclusive, the carbon being generally quite difficult to quantify.

France is one of the countries involved in the future E-RIHS - European Research Infrastructure for Heritage Science. The research infrastructure dedicated to the study of materials of cultural and natural heritage will provide transnational access to state-of-the-art technologies (synchrotron, ion beams, lasers, portable methods, etc.) and scientific archives. E-RIHS addresses the experimental problems of knowledge and conservation of heritage materials (collections of art and natural museums, monuments, archaeological sites, archives, libraries, etc.). The cultural artefacts are characterized by complementary methods at multi-scales. The variety and the hybrid are specific of these artefacts and induce complex problems that are not expected in traditional Natural Science: paints, ceramics and glasses, metals, palaeontological specimens, lithic materials, graphic documents, etc. E-RIHS develops in that purpose transnational access to distributed platforms in many European countries. Five complementary accesses are in this way available: FIXLAB (access to fixed platforms for synchrotron, neutrons, ion beams, lasers, etc.), MOLAB (access to mobile examination and analytical methods to study the works in situ), ARCHLAB (access to scientific archives kept in the cultural institutions), DIGILAB (access to a digital infrastructure for the processing of quantitative data, implementing a policy on (re)use of data, choice of data formats, etc.) and finally EXPERTLAB (panels of experts for the implementation of collaborative and multidisciplinary projects for the study, the analysis and the conservation of heritage works).Thus E-RIHS is specifically involved in complex studies for the development of advanced high-resolution analytical and imaging tools. The privileged field of intervention of the infrastructure is that of the study of large corpora, collections and architectural ensembles. Based on previous I3 European program, and especially IPERION-CH program that support the creation of new mobile instrumentation, the French institutions are involved in the development of LIBS/LIF/RAMAN portable instrumentation. After a presentation of the challenge and the multiple advantages in building the European Infrastructure and of the French E-RIHS hub, the major interests of associating the three lasers based on analytical methods for a more global and precise characterization of the heritage objects taking into account their precious characters and their specific constraints. Lastly some preliminary results will be presented in order to give a first idea of the power of this analytical tool.

Recently, spectral imaging techniques such as Multispectral (MSI) and Hyperspectral Imaging (HSI) have gained importance in the field of heritage conservation. This paper explores the analytical robustness of quantitative chemical imaging for Islamic paper characterization by focusing on the effect of different measurement and processing parameters, i.e. acquisition conditions and calibration on the accuracy of the collected spectral data. This will provide a better understanding of the technique that can provide a measure of change in collections through imaging. For the quantitative model, special calibration target was devised using 105 samples from a well-characterized reference Islamic paper collection. Two material properties were of interest: starch sizing and cellulose degree of polymerization (DP). Multivariate data analysis methods were used to develop discrimination and regression models which were used as an evaluation methodology for the metrology of quantitative NIR chemical imaging. Spectral data were collected using a pushbroom HSI scanner (Gilden Photonics Ltd) in the 1000-2500 nm range with a spectral resolution of 6.3 nm using a mirror scanning setup and halogen illumination. Data were acquired at different measurement conditions and acquisition parameters. Preliminary results showed the potential of the evaluation methodology to show that measurement parameters such as the use of different lenses and different scanning backgrounds may not have a great influence on the quantitative results. Moreover, the evaluation methodology allowed for the selection of the best pre-treatment method to be applied to the data.

The demand for non destructive and non invasive structural diagnostic techniques able to perform on field remote structural evaluation of historical structures and works of art it faces an increased demand. The techniques must have some basic important characteristics The non destructivity, accuracy, repeatability, non physical contact, portability, resolution, broad range of applicability depending on the type of artwork and the question at hand, are all among the important requirements underlying the requirement for on-field structural diagnostics. In this respect there are two known techniques that have been developed at full to provide a suited structural diagnostic application in artwork conservation. The systems presented here but discussed in detail elsewhere are stimulated infrared thermography (SIRT) and digital holographic speckle pattern interferometry (DHSPI) the prior can be found n market at commercial devise level while the latter is at laboratory prototype level. The two systems are being exploited for their complimentary advantages and in this paper are used in combined testing on art related targets according to the above criteria to confirm the enhanced diagnostic information that their complimentary use provides. Results confirm the effectiveness of each technique alone and the combination of data of both techniques in the conservation field. Each system is first briefly described and examples are given with the aim to present the suitability and appropriateness for use in structural documentation analysis and reports. The experimental work is in laboratory work-in-progress focusing on the hybriding of data synthesis.

The X-ray tomographic study was realized in addition to the standard X-ray radiography for the purpose of the new conservation work upon the La Tene culture iron artifacts from the collections of the National Museum in Prague. These artifacts are heavily damaged by the corrosion, avoiding thus an effective visual exploration. The work shows that even details, which are shallow compared to the artifact thickness and therefore not detectable in standard radiographic images, can be made visible in 3D models obtained tomografically. The tomographic data acquisition was performed utilizing the unique TORATOM device, equipped with a large area X-ray detector with Gadox scintillator. The tomographic reconstruction revealed insufficiencies in the earlier conservation processes of the La Tene culture swords, as well as so-far unknown details, such as the exact sword shapes and their decoration. These new findings allowed better classifying of the artifacts. Tomography also helped in visualizing details of iron clips that are completely hidden under the rust, making thus the technology of the clip formation clearly observable. With this work, it has been proven that tomography can bear valuable new information compared to the standard X-ray radiography commonly used in the investigation of iron archeological artifacts.

The present study describes a novel approach to the study of hidden by integrating the non-invasive micro-X-Ray Fluorescence spectroscopy, X-radiography and digital microscopy. The case study analysed is a portrait of a male figure discovered under the painting of Ecce Homo, attributed to Titian’s studio with an estimated date in the 1550s. The X-radiography images exposed the details of the underpainting, which appeared to be a nearly finished portrait of a standing man, overpainted by the current composition of Ecce Homo at a 180° angle. The microscopy observations of the upper painting’s cracks and flaked areas enabled the study of the exposed underlayers in terms of their colour appearance and pigment particles. The subsequent pigment analysis was performed by micro-XRF. Since the described XRF analysis was performed not in scanner mode, the correct selection of the measurement spots for the micro analysis and separation between pigments of the lower and the upper painting was of paramount importance. The described approach for spot selection was based on the results of the preceding X-radiography and digital microscopy tests. The presence of lead white, vermilion, copper green and iron earth in the underlying portrait was confirmed by the multiple point XRF analysis of Pb, Hg, Cu, Fe and Mn lines. The described investigation method proved to be useful in the identification of the pigments of the underlying painting and consequently assisted in the tentative reconstruction of its colour palette. Moreover, the undertaken approach allowed discovering the potential of micro-XRF technique in the study of hidden compositions.

This work contains an overview of infrared thermography (IRT) method and its applications relating to the investigation of architectural structures. In this method, the passive approach is usually used in civil engineering, since it provides a panoramic view of the thermal anomalies to be interpreted also thanks to the use of photographs focused on the region of interest (ROI). The active approach, is more suitable for laboratory or indoor inspections, as well as for objects having a small size. The external stress to be applied is thermal, coming from non-natural apparatus such as lamps or hot / cold air jets. In addition, the latter permits to obtain quantitative information related to defects not detectable to the naked eyes. Very recently, the hybrid thermography (HIRT) approach has been introduced to the attention of the scientific panorama. It can be applied when the radiation coming from the sun, directly arrives (i.e., possibly without the shadow cast effect) on a surface exposed to the air. A large number of thermograms must be collected and a post-processing analysis is subsequently applied via advanced algorithms. Therefore, an appraisal of the defect depth can be obtained passing through the calculation of the combined thermal diffusivity of the materials above the defect. The approach is validated herein by working, in a first stage, on a mosaic sample having known defects while, in a second stage, on a Church built in L’Aquila (Italy) and covered with a particular masonry structure called apparecchio aquilano. The results obtained appear promising.

In Malay world, there is a spirit traditional ritual where they use it as healing practices or for normal life. Malay martial arts (silat) also is not exceptional where some branch of silat have spirit traditional ritual where they said can help them in combat. In this paper, we will not use any ritual, instead we will use some medicinal and environment change when they are performing. There will be 2 performers (fighter) selected, one of them have an experience in martial arts training and another performer does not have experience. Motion Capture (MOCAP) camera will help observe and analyze this move. 8 cameras have been placed in the MOCAP room 2 on each side of the wall facing toward the center of the room from every angle. This will help prevent the loss detection of a marker that been stamped on the limb of a performer. Passive marker has been used where it will reflect the infrared to the camera sensor. Infrared is generated by the source around the camera lens. A 60 kg punching bag was hung on the iron bar function as the target for the performer when throws a punch. Markers also have been stamped on the punching bag so we can detect the movement how far can it swing when hit by the performer. 2 performers will perform 2 moves each with the same position and posture. For every 2 moves, we have made the environment change without the performer notice about it. The first 2 punch with normal environment, second part we have played a positive music to change the performer's mood and third part we have put a medicine (cream/oil) on the skin of the performer. This medicine will make the skin feel a little bit hot. This process repeated to another performer with no experience. The position of this marker analyzed by the Cortex Motion Analysis software where from this data, we can estimate the kinetics and kinematics of the performer. It shows that the increase of kinetics for every part because of the change in the environment, and different result for the 2 performers.