For a purpose of decreasing a defect risk, a primary structure of a polymer such as molecular weight, composition of
comonomer and its sequence plays significantly important roll. Concerning to a typical radical polymerization, molecular
weight and composition are controllable by regulating feed rate of initiator and monomers. At first, a simulation program
predicting the radical polymerization was constructed. Then, the conventional polymerization procedure was modified
by simulation to give the ideal primary structure. After that, the optimized procedure was verified by an actual
experiment. The obtained homogeneous polymer showed good lithographic performance. In addition, a direct
observation of the developed surface was achieved by scanning probe microscopy.
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